A study of the transdermal drug diffusion properties of rooperol tetra-acetate
- Authors: Pefile, Sibongile C.
- Date: 1998 , 2013-08-29
- Subjects: Transdermal medication , Skin absorption , Dermatologic agents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3838 , http://hdl.handle.net/10962/d1007649 , Transdermal medication , Skin absorption , Dermatologic agents
- Description: The rapidly growing interest in the potential use of topical drug delivery formulations has resulted in increased use of the skin as a vital port for drug delivery. Extensive research has been conducted in designing vehicles capable of delivering a desired amount of drug to a specific site, to produce the desired pharmacological response. Rooperol tetra-acetate is a lipophilic, cytotoxic drug with the potential for use in the treatment of solar keratosis. For effective pharmacological action, delivery of the drug to the epidermal/dermal junction of the skin is required. A study of the topical penetration properties of rooperol tetra-acetate from different topical bases, each possessing different physico-chemical properties, was performed. The assessment involved a comparison of the diffusion properties under occlusive and non occlusive conditions when the drug was formulated into a gel, Cetomacrogol Cream B.P. (oil-inwater), Simple Ointment B.P. and an extemporaneously prepared water-in-oil topical cream. The in vitro experiments were conducted using polydimethylsiloxane and rat membrane mounted in a Franz diffusion cell. The topical permeation kinetics of rooperol tetra-acetate were determined by exploring the release characteristics of the active ingredient from the vehicles formulated and the permeability properties of the drug through the membranes employed. Further studies involved investigating the utilization of supersaturated systems intended to increase the thermodynamic activity of the drug when formulated into a propylene glycol/water vehicle (with and without polymer). To measure the release of rooperol tetra-acetate into the skin from a topical base it was necessary to, firstly, develop a suitable quantitative method for the analysis of the active drug in the aqueous receptor phase of in vitro diffusion cells. The second stage of product development was the design of an effective delivery system to facilitate the release of the diffusant from its base. A high performance liquid chromatographic method was utilized for the identification and quantification of the active drug. As validation is an important aspect in the development and subsequent utilization of an analytical procedure, the developed HPLC technique was validated by determining the precision, accuracy, range, limit of quantitation and sensitivity of the system. Lastly, the stability of rooperol tetra-acetate at elevated temperatures was assessed and a stability profile of the drug was generated for the three-month period of analysis. The results obtained following chromatographic analysis of the receptor phase sampled during the diffusion experiments indicate that the gel and oil-in-water formulations most effectively promoted the diffusion of rooperol tetra-acetate across polydimethylsiloxane membrane. The water-in-oil system exhibited lower flux rates and the ointment showed the least drug release. Occlusion of the topical vehicle increased the diffusitivity of the permeant from all formulations analysed. The permeation assessment results of the supersaturated systems showed enhanced diffusion of rooperol tetra-acetate across polydimethylsiloxane and rat membrane. The high thermodynamic activity existing in supersaturated systems most effectively increased the driving force for drug diffusion resulting in enhanced percutaneous penetration of rooperol tetra-acetate beyond the release and transport limitations of saturated solutions. These results provide the basis on which an effective topical drug delivery vehicle may be designed for this new drug entity.
- Full Text:
- Date Issued: 1998
- Authors: Pefile, Sibongile C.
- Date: 1998 , 2013-08-29
- Subjects: Transdermal medication , Skin absorption , Dermatologic agents
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:3838 , http://hdl.handle.net/10962/d1007649 , Transdermal medication , Skin absorption , Dermatologic agents
- Description: The rapidly growing interest in the potential use of topical drug delivery formulations has resulted in increased use of the skin as a vital port for drug delivery. Extensive research has been conducted in designing vehicles capable of delivering a desired amount of drug to a specific site, to produce the desired pharmacological response. Rooperol tetra-acetate is a lipophilic, cytotoxic drug with the potential for use in the treatment of solar keratosis. For effective pharmacological action, delivery of the drug to the epidermal/dermal junction of the skin is required. A study of the topical penetration properties of rooperol tetra-acetate from different topical bases, each possessing different physico-chemical properties, was performed. The assessment involved a comparison of the diffusion properties under occlusive and non occlusive conditions when the drug was formulated into a gel, Cetomacrogol Cream B.P. (oil-inwater), Simple Ointment B.P. and an extemporaneously prepared water-in-oil topical cream. The in vitro experiments were conducted using polydimethylsiloxane and rat membrane mounted in a Franz diffusion cell. The topical permeation kinetics of rooperol tetra-acetate were determined by exploring the release characteristics of the active ingredient from the vehicles formulated and the permeability properties of the drug through the membranes employed. Further studies involved investigating the utilization of supersaturated systems intended to increase the thermodynamic activity of the drug when formulated into a propylene glycol/water vehicle (with and without polymer). To measure the release of rooperol tetra-acetate into the skin from a topical base it was necessary to, firstly, develop a suitable quantitative method for the analysis of the active drug in the aqueous receptor phase of in vitro diffusion cells. The second stage of product development was the design of an effective delivery system to facilitate the release of the diffusant from its base. A high performance liquid chromatographic method was utilized for the identification and quantification of the active drug. As validation is an important aspect in the development and subsequent utilization of an analytical procedure, the developed HPLC technique was validated by determining the precision, accuracy, range, limit of quantitation and sensitivity of the system. Lastly, the stability of rooperol tetra-acetate at elevated temperatures was assessed and a stability profile of the drug was generated for the three-month period of analysis. The results obtained following chromatographic analysis of the receptor phase sampled during the diffusion experiments indicate that the gel and oil-in-water formulations most effectively promoted the diffusion of rooperol tetra-acetate across polydimethylsiloxane membrane. The water-in-oil system exhibited lower flux rates and the ointment showed the least drug release. Occlusion of the topical vehicle increased the diffusitivity of the permeant from all formulations analysed. The permeation assessment results of the supersaturated systems showed enhanced diffusion of rooperol tetra-acetate across polydimethylsiloxane and rat membrane. The high thermodynamic activity existing in supersaturated systems most effectively increased the driving force for drug diffusion resulting in enhanced percutaneous penetration of rooperol tetra-acetate beyond the release and transport limitations of saturated solutions. These results provide the basis on which an effective topical drug delivery vehicle may be designed for this new drug entity.
- Full Text:
- Date Issued: 1998
An analysis of the use of DNS for malicious payload distribution
- Authors: Dube, Ishmael
- Date: 2019
- Subjects: Internet domain names , Computer networks -- Security measures , Computer security , Computer network protocols , Data protection
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/97531 , vital:31447
- Description: The Domain Name System (DNS) protocol is a fundamental part of Internet activities that can be abused by cybercriminals to conduct malicious activities. Previous research has shown that cybercriminals use different methods, including the DNS protocol, to distribute malicious content, remain hidden and avoid detection from various technologies that are put in place to detect anomalies. This allows botnets and certain malware families to establish covert communication channels that can be used to send or receive data and also distribute malicious payloads using the DNS queries and responses. Cybercriminals use the DNS to breach highly protected networks, distribute malicious content, and exfiltrate sensitive information without being detected by security controls put in place by embedding certain strings in DNS packets. This research undertaking broadens this research field and fills in the existing research gap by extending the analysis of DNS being used as a payload distribution channel to detection of domains that are used to distribute different malicious payloads. This research undertaking analysed the use of the DNS in detecting domains and channels that are used for distributing malicious payloads. Passive DNS data which replicate DNS queries on name servers to detect anomalies in DNS queries was evaluated and analysed in order to detect malicious payloads. The research characterises the malicious payload distribution channels by analysing passive DNS traffic and modelling the DNS query and response patterns. The research found that it is possible to detect malicious payload distribution channels through the analysis of DNS TXT resource records.
- Full Text:
- Date Issued: 2019
- Authors: Dube, Ishmael
- Date: 2019
- Subjects: Internet domain names , Computer networks -- Security measures , Computer security , Computer network protocols , Data protection
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/97531 , vital:31447
- Description: The Domain Name System (DNS) protocol is a fundamental part of Internet activities that can be abused by cybercriminals to conduct malicious activities. Previous research has shown that cybercriminals use different methods, including the DNS protocol, to distribute malicious content, remain hidden and avoid detection from various technologies that are put in place to detect anomalies. This allows botnets and certain malware families to establish covert communication channels that can be used to send or receive data and also distribute malicious payloads using the DNS queries and responses. Cybercriminals use the DNS to breach highly protected networks, distribute malicious content, and exfiltrate sensitive information without being detected by security controls put in place by embedding certain strings in DNS packets. This research undertaking broadens this research field and fills in the existing research gap by extending the analysis of DNS being used as a payload distribution channel to detection of domains that are used to distribute different malicious payloads. This research undertaking analysed the use of the DNS in detecting domains and channels that are used for distributing malicious payloads. Passive DNS data which replicate DNS queries on name servers to detect anomalies in DNS queries was evaluated and analysed in order to detect malicious payloads. The research characterises the malicious payload distribution channels by analysing passive DNS traffic and modelling the DNS query and response patterns. The research found that it is possible to detect malicious payload distribution channels through the analysis of DNS TXT resource records.
- Full Text:
- Date Issued: 2019
Mozart and the language of contrast : a study of four early piano concertos
- Correia, João Eduardo de Jesus
- Authors: Correia, João Eduardo de Jesus
- Date: 1987 , 2013-04-04
- Subjects: Mozart, Wolfgang Amadeus, 1756-1791. Concertos, piano, orchestra
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:2668 , http://hdl.handle.net/10962/d1006863 , Mozart, Wolfgang Amadeus, 1756-1791. Concertos, piano, orchestra
- Full Text:
- Date Issued: 1987
- Authors: Correia, João Eduardo de Jesus
- Date: 1987 , 2013-04-04
- Subjects: Mozart, Wolfgang Amadeus, 1756-1791. Concertos, piano, orchestra
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:2668 , http://hdl.handle.net/10962/d1006863 , Mozart, Wolfgang Amadeus, 1756-1791. Concertos, piano, orchestra
- Full Text:
- Date Issued: 1987
Geochemical exploration in arid and semi-arid environments
- Authors: Van Berkel, Ferdinand
- Date: 1983 , 2013-04-02
- Subjects: Geochemical prospecting , Arid regions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4920 , http://hdl.handle.net/10962/d1004389 , Geochemical prospecting , Arid regions
- Description: Anomalous element distributions within the regolith result from chemical adjustments of the earth's surface to prevailing climatic conditions. Because of the lack of moisture in the arid environment, chemical equilibrium related to paleoclimates is largely maintained. Mechanical or clastic dispersion dominates arid weathering and hence the exploration approach is largely dictated by the degree of preservation of the paleoregolith. Arid environment geochemists thus have to contend with surface materials ranging from laterite and calcrete in areas where the imprint of aridity is minimal, to more conventional sample media such as bedrock, stream sediment and lithic soils in actively dissecting areas. Extraction techniques are designed specifically to isolate clastic dispersion trains. Thick mantles of aeolian and water-borne overburden characterise desert lowlands and are a challenge to the exploration geochemist. Techniques showing the most promise in these areas include groundwater geochemistry, vapour geochemistry, surface microlayer geochemistry, geobotany and biogeochemistry which attempt to isolate gaseous and weak hydromorphic, ore-related trace-element dispersions. Termite mound sampling yields convincing results and appears to be an under-utilised geochemical approach. , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1983
- Authors: Van Berkel, Ferdinand
- Date: 1983 , 2013-04-02
- Subjects: Geochemical prospecting , Arid regions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4920 , http://hdl.handle.net/10962/d1004389 , Geochemical prospecting , Arid regions
- Description: Anomalous element distributions within the regolith result from chemical adjustments of the earth's surface to prevailing climatic conditions. Because of the lack of moisture in the arid environment, chemical equilibrium related to paleoclimates is largely maintained. Mechanical or clastic dispersion dominates arid weathering and hence the exploration approach is largely dictated by the degree of preservation of the paleoregolith. Arid environment geochemists thus have to contend with surface materials ranging from laterite and calcrete in areas where the imprint of aridity is minimal, to more conventional sample media such as bedrock, stream sediment and lithic soils in actively dissecting areas. Extraction techniques are designed specifically to isolate clastic dispersion trains. Thick mantles of aeolian and water-borne overburden characterise desert lowlands and are a challenge to the exploration geochemist. Techniques showing the most promise in these areas include groundwater geochemistry, vapour geochemistry, surface microlayer geochemistry, geobotany and biogeochemistry which attempt to isolate gaseous and weak hydromorphic, ore-related trace-element dispersions. Termite mound sampling yields convincing results and appears to be an under-utilised geochemical approach. , KMBT_363 , Adobe Acrobat 9.53 Paper Capture Plug-in
- Full Text:
- Date Issued: 1983
Developing high-fidelity mental models of programming concepts using manipulatives and interactive metaphors
- Authors: Funcke, Matthew
- Date: 2015
- Subjects: Computer programming -- Study and teaching (Higher) , Computer programmers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4707 , http://hdl.handle.net/10962/d1017929
- Description: It is well established that both learning and teaching programming are difficult tasks. Difficulties often occur due to weak mental models and common misconceptions. This study proposes a method of teaching programming that both encourages high-fidelity mental models and attempts to minimise misconceptions in novice programmers, through the use of metaphors and manipulatives. The elements in ActionWorld with which the students interact are realizations of metaphors. By simple example, a variable has a metaphorical representation as a labelled box that can hold a value. The dissertation develops a set of metaphors which have several core requirements: metaphors should avoid causing misconceptions, they need to be high-fidelity so as to avoid failing when used with a new concept, students must be able to relate to them, and finally, they should be usable across multiple educational media. The learning style that ActionWorld supports is one which requires active participation from the student - the system acts as a foundation upon which students are encouraged to build their mental models. This teaching style is achieved by placing the student in the role of code interpreter, the code they need to interpret will not advance until they have demonstrated its meaning via use of the aforementioned metaphors. ActionWorld was developed using an iterative developmental process that consistently improved upon various aspects of the project through a continual evaluation-enhancement cycle. The primary outputs of this project include a unified set of high-fidelity metaphors, a virtual-machine API for use in similar future projects, and two metaphor-testing games. All of the aforementioned deliverables were tested using multiple quality-evaluation criteria, the results of which were consistently positive. ActionWorld and its constituent components contribute to the wide assortment of methods one might use to teach novice programmers.
- Full Text:
- Date Issued: 2015
- Authors: Funcke, Matthew
- Date: 2015
- Subjects: Computer programming -- Study and teaching (Higher) , Computer programmers
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4707 , http://hdl.handle.net/10962/d1017929
- Description: It is well established that both learning and teaching programming are difficult tasks. Difficulties often occur due to weak mental models and common misconceptions. This study proposes a method of teaching programming that both encourages high-fidelity mental models and attempts to minimise misconceptions in novice programmers, through the use of metaphors and manipulatives. The elements in ActionWorld with which the students interact are realizations of metaphors. By simple example, a variable has a metaphorical representation as a labelled box that can hold a value. The dissertation develops a set of metaphors which have several core requirements: metaphors should avoid causing misconceptions, they need to be high-fidelity so as to avoid failing when used with a new concept, students must be able to relate to them, and finally, they should be usable across multiple educational media. The learning style that ActionWorld supports is one which requires active participation from the student - the system acts as a foundation upon which students are encouraged to build their mental models. This teaching style is achieved by placing the student in the role of code interpreter, the code they need to interpret will not advance until they have demonstrated its meaning via use of the aforementioned metaphors. ActionWorld was developed using an iterative developmental process that consistently improved upon various aspects of the project through a continual evaluation-enhancement cycle. The primary outputs of this project include a unified set of high-fidelity metaphors, a virtual-machine API for use in similar future projects, and two metaphor-testing games. All of the aforementioned deliverables were tested using multiple quality-evaluation criteria, the results of which were consistently positive. ActionWorld and its constituent components contribute to the wide assortment of methods one might use to teach novice programmers.
- Full Text:
- Date Issued: 2015
DRUBIS : a distributed face-identification experimentation framework - design, implementation and performance issues
- Authors: Ndlangisa, Mboneli
- Date: 2004
- Subjects: Principal components analysis , Human face recognition (Computer science) , Image processing , Biometric identification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4704 , http://hdl.handle.net/10962/d1015768
- Description: We report on the design, implementation and performance issues of the DRUBIS (Distributed Rhodes University Biometric Identification System) experimentation framework. The Principal Component Analysis (PCA) face-recognition approach is used as a case study. DRUBIS is a flexible experimentation framework, distributed over a number of modules that are easily pluggable and swappable, allowing for the easy construction of prototype systems. Web services are the logical means of distributing DRUBIS components and a number of prototype applications have been implemented from this framework. Different popular PCA face-recognition related experiments were used to evaluate our experimentation framework. We extract recognition performance measures from these experiments. In particular, we use the framework for a more indepth study of the suitability of the DFFS (Difference From Face Space) metric as a means for image classification in the area of race and gender determination.
- Full Text:
- Date Issued: 2004
- Authors: Ndlangisa, Mboneli
- Date: 2004
- Subjects: Principal components analysis , Human face recognition (Computer science) , Image processing , Biometric identification
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4704 , http://hdl.handle.net/10962/d1015768
- Description: We report on the design, implementation and performance issues of the DRUBIS (Distributed Rhodes University Biometric Identification System) experimentation framework. The Principal Component Analysis (PCA) face-recognition approach is used as a case study. DRUBIS is a flexible experimentation framework, distributed over a number of modules that are easily pluggable and swappable, allowing for the easy construction of prototype systems. Web services are the logical means of distributing DRUBIS components and a number of prototype applications have been implemented from this framework. Different popular PCA face-recognition related experiments were used to evaluate our experimentation framework. We extract recognition performance measures from these experiments. In particular, we use the framework for a more indepth study of the suitability of the DFFS (Difference From Face Space) metric as a means for image classification in the area of race and gender determination.
- Full Text:
- Date Issued: 2004
The impact of the construction regulations 2014 on a water utility’s projects’ health and safety performance in South Africa
- Authors: Malindi, Rajandree Mandy
- Date: 2018
- Subjects: Construction industry -- Safety regulations -- South Africa , Construction industry -- Standards -- South Africa Construction industry -- Law and legislation -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/31655 , vital:31645
- Description: The construction industry plays a major role in South Africa’s economic development. Since promulgation of the Construction Regulations, the expectation is that project stakeholders are placing more emphasis on H&S to contribute to project success. The study aimed to assess the impact of the involvement of clients and other project stakeholders on the overall project H&S performance on projects undertaken by a large water utility. The scope was limited to the organisation’s engineering and operations division and its internal project stakeholders, namely the designers, quantity surveyors, project managers, and construction H&S professionals. Local literature pointed out that poor construction H&S performance is attributable to a lack of management commitment, inadequate supervision, inadequate or lack of H&S training, lack of worker involvement, personal risk appreciation and work pressures (cidb, 2009: 37). International literature indicated that the total CoA exceeds the cost of H&S (cidb, 2009: 9). Quantitative methods were utilised in two phases to gather and analyse data. In Phase 1, a questionnaire was developed and distributed to a target population, and in Phase 2, data was obtained from existing records of historic and completed project files for projects undertaken by the water utility. A total of 67 responses were used to analyse data. All stakeholders somehow contributed to H&S however, most respondents regarded CHS professionals, contractors and PMs as the primary stakeholders. The study found that stakeholders perceived H&S to be influenced during the later rather than the initial stages of projects and that H&S actions were significantly undertaken during stage 5. The frequency of H&S actions varied with each stakeholder dependent on the stage in which they were involved in. Recommendations were for H&S to be integrated in the initial stages of projects and for a follow up research to be conducted to investigate if there are improvements during the six project stages after full implementation of the Construction Regulations 2014. This requirement will force industry to comply and most importantly to drive joint efforts by the various stakeholders.
- Full Text:
- Date Issued: 2018
- Authors: Malindi, Rajandree Mandy
- Date: 2018
- Subjects: Construction industry -- Safety regulations -- South Africa , Construction industry -- Standards -- South Africa Construction industry -- Law and legislation -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/31655 , vital:31645
- Description: The construction industry plays a major role in South Africa’s economic development. Since promulgation of the Construction Regulations, the expectation is that project stakeholders are placing more emphasis on H&S to contribute to project success. The study aimed to assess the impact of the involvement of clients and other project stakeholders on the overall project H&S performance on projects undertaken by a large water utility. The scope was limited to the organisation’s engineering and operations division and its internal project stakeholders, namely the designers, quantity surveyors, project managers, and construction H&S professionals. Local literature pointed out that poor construction H&S performance is attributable to a lack of management commitment, inadequate supervision, inadequate or lack of H&S training, lack of worker involvement, personal risk appreciation and work pressures (cidb, 2009: 37). International literature indicated that the total CoA exceeds the cost of H&S (cidb, 2009: 9). Quantitative methods were utilised in two phases to gather and analyse data. In Phase 1, a questionnaire was developed and distributed to a target population, and in Phase 2, data was obtained from existing records of historic and completed project files for projects undertaken by the water utility. A total of 67 responses were used to analyse data. All stakeholders somehow contributed to H&S however, most respondents regarded CHS professionals, contractors and PMs as the primary stakeholders. The study found that stakeholders perceived H&S to be influenced during the later rather than the initial stages of projects and that H&S actions were significantly undertaken during stage 5. The frequency of H&S actions varied with each stakeholder dependent on the stage in which they were involved in. Recommendations were for H&S to be integrated in the initial stages of projects and for a follow up research to be conducted to investigate if there are improvements during the six project stages after full implementation of the Construction Regulations 2014. This requirement will force industry to comply and most importantly to drive joint efforts by the various stakeholders.
- Full Text:
- Date Issued: 2018
Interactions between fig wasps and their host figs
- Authors: Nefdt, Rory John Charlton
- Date: 1990
- Subjects: Wasps , Mutualism (Biology)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5718 , http://hdl.handle.net/10962/d1005404 , Wasps , Mutualism (Biology)
- Description: Fig trees (Ficus spp.) and fig wasps (Hymenoptera: Agaonidae) are partners in an intimate mutualism. The trees provide ovules in which wasp larvae develop while the wasps pollinate the flowers and are therefore indispensible for fig seed production. Agaonid fig wasps oviposit down the styles of fig flowers and it has generally been accepted that they were unable to reach the ovules of "long" styled flowers , which would produce seeds, thus maintaining an evolutionary stable mutualism. African fig species were found to have unimodal style length frequencies, with no separation into long and short styled flowers. In several species the ovipositors of their associated agaonids were long enough to reach the majority of ovules. The number of foundress agaonids entering a fig influenced fig seed set and therefore was an important factor regulating the proportion of flowers producing seeds or pollinators. In the two Ficus species that were studied, entry of more than three agaonid foundresses into one fig resulted in competition for limited oviposition sites and less female - biased offspring sex ratios. It is hypothesised that sequential laying of male eggs followed by female eggs, under variable oviposition site limitation, results in sex ratio adjustment, as predicted by local mate competition theory. Evidence in support of this hypothesis is presented. A number of non - pollinating torymid and pteromalid fig wasps also oviposit into each fig species. The sycophagines and sycoecines oviposit down the styles from inside the fig inflorescences like their agaonid counterparts, while other species insert their ovipositors through the wall of the fig from the outside. Like the agaonids, sycophagines were characterised by being pro - ovigenic, with numerous fully developed eggs at emergence. Sycoecines were able to re - emerge from figs they had oviposited in and lay their eggs in more than one fig. They had short ovipositors, allowing access to a smaller proportion of flowers than agaonids or sycophagines. Externally ovipositing fig wasps were syn-ovigenic, able to develop eggs as adults and invested more energy and time during each oviposition event. Differences in the ovipositor lengths of these species did not segregate their oviposition sites spatially, and therefore does not reduce competition between species. Attack by parasitoids and inquiline fig wasps from the exterior did not constitute a selection pressure against agaonids ovipositing in ovules closer to the periphery of the fig's surface, as predicted by Michaloud's enemy-free-space hypothes is. It cannot therefore explain the preference shown by ovipositing agaonids for shorter styled flowers.
- Full Text:
- Date Issued: 1990
- Authors: Nefdt, Rory John Charlton
- Date: 1990
- Subjects: Wasps , Mutualism (Biology)
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5718 , http://hdl.handle.net/10962/d1005404 , Wasps , Mutualism (Biology)
- Description: Fig trees (Ficus spp.) and fig wasps (Hymenoptera: Agaonidae) are partners in an intimate mutualism. The trees provide ovules in which wasp larvae develop while the wasps pollinate the flowers and are therefore indispensible for fig seed production. Agaonid fig wasps oviposit down the styles of fig flowers and it has generally been accepted that they were unable to reach the ovules of "long" styled flowers , which would produce seeds, thus maintaining an evolutionary stable mutualism. African fig species were found to have unimodal style length frequencies, with no separation into long and short styled flowers. In several species the ovipositors of their associated agaonids were long enough to reach the majority of ovules. The number of foundress agaonids entering a fig influenced fig seed set and therefore was an important factor regulating the proportion of flowers producing seeds or pollinators. In the two Ficus species that were studied, entry of more than three agaonid foundresses into one fig resulted in competition for limited oviposition sites and less female - biased offspring sex ratios. It is hypothesised that sequential laying of male eggs followed by female eggs, under variable oviposition site limitation, results in sex ratio adjustment, as predicted by local mate competition theory. Evidence in support of this hypothesis is presented. A number of non - pollinating torymid and pteromalid fig wasps also oviposit into each fig species. The sycophagines and sycoecines oviposit down the styles from inside the fig inflorescences like their agaonid counterparts, while other species insert their ovipositors through the wall of the fig from the outside. Like the agaonids, sycophagines were characterised by being pro - ovigenic, with numerous fully developed eggs at emergence. Sycoecines were able to re - emerge from figs they had oviposited in and lay their eggs in more than one fig. They had short ovipositors, allowing access to a smaller proportion of flowers than agaonids or sycophagines. Externally ovipositing fig wasps were syn-ovigenic, able to develop eggs as adults and invested more energy and time during each oviposition event. Differences in the ovipositor lengths of these species did not segregate their oviposition sites spatially, and therefore does not reduce competition between species. Attack by parasitoids and inquiline fig wasps from the exterior did not constitute a selection pressure against agaonids ovipositing in ovules closer to the periphery of the fig's surface, as predicted by Michaloud's enemy-free-space hypothes is. It cannot therefore explain the preference shown by ovipositing agaonids for shorter styled flowers.
- Full Text:
- Date Issued: 1990
A study of the fluorescence excitation spectrum of crystalline anthracene
- Authors: Driver, Adrian Stanford
- Date: 1960
- Subjects: Fluorimetry , Anthracene crystals -- Spectra
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5518 , http://hdl.handle.net/10962/d1011463 , Fluorimetry , Anthracene crystals -- Spectra
- Description: The work described in this thesis was performed at the Physics Department, Rhodes University during 1958 and 1959 under the supervision of Professor J.A. Gledhill. Use was made of a vacuum ultra-violet spectrograph which had been constructed in the Physics Department (1.1) and modifications to be described were made to this instrument. The instrument was used for studying the effects of oxygen on the fluorescence excitation spectrum of Anthracene.
- Full Text:
- Date Issued: 1960
- Authors: Driver, Adrian Stanford
- Date: 1960
- Subjects: Fluorimetry , Anthracene crystals -- Spectra
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5518 , http://hdl.handle.net/10962/d1011463 , Fluorimetry , Anthracene crystals -- Spectra
- Description: The work described in this thesis was performed at the Physics Department, Rhodes University during 1958 and 1959 under the supervision of Professor J.A. Gledhill. Use was made of a vacuum ultra-violet spectrograph which had been constructed in the Physics Department (1.1) and modifications to be described were made to this instrument. The instrument was used for studying the effects of oxygen on the fluorescence excitation spectrum of Anthracene.
- Full Text:
- Date Issued: 1960
Predicting reintroduction outcomes: assessing the feasibility of reintroducing African wild dog to a small protected area
- Authors: Vogel, John Thomas
- Date: 2018
- Subjects: African wild dog , Wild dogs -- South Africa Wild dogs -- Conservation -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/36464 , vital:33947
- Description: Large mammalian carnivores have experienced significant contractions in population sizes and geographical ranges. The conservation of large carnivores is crucially important, particularly due to their vulnerability to extinction and their functional significance and ability to structure ecosystems. Due to an expanding human footprint, large carnivores are increasingly subject to modified and spatially constrained habitats. A growing debate exists as to how to conserve and coexist with large carnivores in an anthropogenically induced environment. Reintroduction, as a conservation tool to restore locally extirpated large carnivores to portions of their former ranges is increasingly being applied. However, in South Africa, habitat to support large carnivores remain small and non-contiguous. Food is a fundamental ecological requirement to sustain reintroduced large carnivores. Therefore, an understanding of large predator foraging patterns can be informative in the context of how the predator species influences and utilises a novel ecosystem. We investigated the foraging behaviour of reintroduced African wild dog (Lycaon pictus) at five small protected areas in KwaZulu-Natal, South Africa. Wild dog utilised 16 prey species, albeit they primarily used nyala (Tragelaphus angasii) and impala (Aepyceros melampus) which collectively form 75 % of their diet. Only nyala was significantly preferred, suggesting that this prey species is used in greater proportion to their abundance. As wild dogs are social cooperative hunters, we tested whether wild dog pack size was correlated to prey mass selection. There was no evidence to suggest that larger packs use larger prey. However, the mean wild dog pack size in our sample sites, was relatively smaller than those encountered elsewhere. Furthermore, wild dog have been shown to modify their hunting behaviour in the presence of wildlife-proof fencing, by using fences to aid in the capture of larger prey species than would innately occur. We compared the prey mass of wild dog kills in relation to proximity of these hard boundaries. Despite the affinity towards kills occurring within 200 m of fences, the upward bias caused by fences on prey mass selection was inconsistent across sample sites. The relatively small size of wild dogs makes them particularly vulnerable to competition. As the energetic output of wild dog is high, interspecific competition can increase foraging costs. The reintroduction of large carnivores to small artificially induced systems may be a contentious issue as resources available to support large carnivores are expected to be relatively more finite. We compared both the potential inter- and intraspecific dietary niche dimensions of an intact large carnivore guild in context of a wild dog reintroduction. We determined cheetah (Acinonyx jubatus), leopard (Panthera pardus), and lion (Panthera leo) prey composition, diet breadth, overlap, prey preference and predicted the density of an intact large carnivore guild in a novel landscape. Further, we compared the foraging behaviour of these large carnivores to that of wild dog. Our findings suggest that large African carnivores in small protected areas are subject to a considerable dietary niche overlap. Wild dog and cheetah, particularly reproductive females with dependent offspring, displayed the greatest potential for dietary overlap and subsequent competition. Leopard and lion at the population species level exhibited greater degrees of foraging plasticity. Lion displayed a contrasting prey species preference to sympatric predators as they selected for prey items frequently avoided by cheetah, leopard and wild dog. The proposed wild dog reintroduction site is expected to sustain seven wild dog based on the availability of preferred prey biomass. However, the reintroduction of wild dog to the small protected area is expected to have negative lateral trophic influences on other species of conservation concern. This should be of vital importance to management of the protected area. As the influence of competition in food-web and population dynamics, particularly in resource poor environments may be profound, our research highlights the need to assess the influence of competitive forces in structuring and restoring large predators to portions of their historical range.
- Full Text:
- Date Issued: 2018
- Authors: Vogel, John Thomas
- Date: 2018
- Subjects: African wild dog , Wild dogs -- South Africa Wild dogs -- Conservation -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/36464 , vital:33947
- Description: Large mammalian carnivores have experienced significant contractions in population sizes and geographical ranges. The conservation of large carnivores is crucially important, particularly due to their vulnerability to extinction and their functional significance and ability to structure ecosystems. Due to an expanding human footprint, large carnivores are increasingly subject to modified and spatially constrained habitats. A growing debate exists as to how to conserve and coexist with large carnivores in an anthropogenically induced environment. Reintroduction, as a conservation tool to restore locally extirpated large carnivores to portions of their former ranges is increasingly being applied. However, in South Africa, habitat to support large carnivores remain small and non-contiguous. Food is a fundamental ecological requirement to sustain reintroduced large carnivores. Therefore, an understanding of large predator foraging patterns can be informative in the context of how the predator species influences and utilises a novel ecosystem. We investigated the foraging behaviour of reintroduced African wild dog (Lycaon pictus) at five small protected areas in KwaZulu-Natal, South Africa. Wild dog utilised 16 prey species, albeit they primarily used nyala (Tragelaphus angasii) and impala (Aepyceros melampus) which collectively form 75 % of their diet. Only nyala was significantly preferred, suggesting that this prey species is used in greater proportion to their abundance. As wild dogs are social cooperative hunters, we tested whether wild dog pack size was correlated to prey mass selection. There was no evidence to suggest that larger packs use larger prey. However, the mean wild dog pack size in our sample sites, was relatively smaller than those encountered elsewhere. Furthermore, wild dog have been shown to modify their hunting behaviour in the presence of wildlife-proof fencing, by using fences to aid in the capture of larger prey species than would innately occur. We compared the prey mass of wild dog kills in relation to proximity of these hard boundaries. Despite the affinity towards kills occurring within 200 m of fences, the upward bias caused by fences on prey mass selection was inconsistent across sample sites. The relatively small size of wild dogs makes them particularly vulnerable to competition. As the energetic output of wild dog is high, interspecific competition can increase foraging costs. The reintroduction of large carnivores to small artificially induced systems may be a contentious issue as resources available to support large carnivores are expected to be relatively more finite. We compared both the potential inter- and intraspecific dietary niche dimensions of an intact large carnivore guild in context of a wild dog reintroduction. We determined cheetah (Acinonyx jubatus), leopard (Panthera pardus), and lion (Panthera leo) prey composition, diet breadth, overlap, prey preference and predicted the density of an intact large carnivore guild in a novel landscape. Further, we compared the foraging behaviour of these large carnivores to that of wild dog. Our findings suggest that large African carnivores in small protected areas are subject to a considerable dietary niche overlap. Wild dog and cheetah, particularly reproductive females with dependent offspring, displayed the greatest potential for dietary overlap and subsequent competition. Leopard and lion at the population species level exhibited greater degrees of foraging plasticity. Lion displayed a contrasting prey species preference to sympatric predators as they selected for prey items frequently avoided by cheetah, leopard and wild dog. The proposed wild dog reintroduction site is expected to sustain seven wild dog based on the availability of preferred prey biomass. However, the reintroduction of wild dog to the small protected area is expected to have negative lateral trophic influences on other species of conservation concern. This should be of vital importance to management of the protected area. As the influence of competition in food-web and population dynamics, particularly in resource poor environments may be profound, our research highlights the need to assess the influence of competitive forces in structuring and restoring large predators to portions of their historical range.
- Full Text:
- Date Issued: 2018
The social and spatial organisation of the Greater kudu (Tragelaphus strepsiceros Pallas 1766) in the Andries Vosloo Kudu Reserve, Eastern Cape
- Authors: Allen-Rowlandson, T S
- Date: 1981
- Subjects: Greater kudu -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5614 , http://hdl.handle.net/10962/d1003120 , Greater kudu -- South Africa -- Eastern Cape
- Description: Methods of capture, marking and age determination in the field, were investigated. The density and structure of the population, individual movements and social relationships were determined. Aspects of reproduction examined included age at puberty, agespecific fecundity, calving intervals and seasonality. Temporal changes in the spatial and social organisation are discussed in relation to environmental conditions, reproduction and population structure. Factors influencing the fecundity, dynamics and grouping patterns within the population are considered.
- Full Text:
- Date Issued: 1981
- Authors: Allen-Rowlandson, T S
- Date: 1981
- Subjects: Greater kudu -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5614 , http://hdl.handle.net/10962/d1003120 , Greater kudu -- South Africa -- Eastern Cape
- Description: Methods of capture, marking and age determination in the field, were investigated. The density and structure of the population, individual movements and social relationships were determined. Aspects of reproduction examined included age at puberty, agespecific fecundity, calving intervals and seasonality. Temporal changes in the spatial and social organisation are discussed in relation to environmental conditions, reproduction and population structure. Factors influencing the fecundity, dynamics and grouping patterns within the population are considered.
- Full Text:
- Date Issued: 1981
Exploration for stratabound copper, lead and zinc deposits in the Damara-Katanga orogen, central-southern Africa
- Authors: Latorre, J J
- Date: 1992
- Subjects: Mining geology -- Research -- Africa , Copper ores -- Africa , Lead ores -- Africa , Zinc ores -- Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4946 , http://hdl.handle.net/10962/d1005558
- Description: The Damara-Katanga orogen in central-southern Africa represents an area of 1.73xl0⁶ sq. km. The region is considered one of the wealthiest metallogenic provinces in the world. Successful exploration for stratabound base-metal deposits has taken place at this particular area since the introduction of more organised methodology in the early 1920s. The genesis, location and distribution of the ore deposits are related to their tectonic settings. Geodynamic evolution of the orogen, which initially formed part of a complex Pan-African rift system, comprises the following stages rifting; downwarping, including spreading on the western portion; syn-orogeny and late-orogeny. Two major tectonic events in the history of the region have been identified: the Katangan (900-750 Ma) and the Damaran episodes (750-500 Ma). Timing of mineralisation of ore deposits has been related to the evolutionary stages of the orogen. Genetic models of the most productive deposits are briefly discussed in this dissertation. The sedimentological, geochemical, paleogeographic and structural features can be employed as geological guidelines for integrated exploration programmes. Discoveries of major deposits and prospects in the orogen are also summarised, focussing on the exploration methods employed. The cost-effective use of the exploration techniques includes the classical copper-lead-zinc soil sampling for residual soils such as those in the Copperbelt area. Airborne magnetics and electromagnetics and follow-up ground geophysics have proved successful in areas where the cover is transported in the search for shallow ore deposits such as the Matchless massive sulphides. Remote sensing, geochemical and geophysical techniques have been tried in covered areas of western Botswana. The lack of geological control makes this interpretation difficult. A detailed geological mapping and the use of geochemical and geophysical techniques has been used to delineate carbonate-hosted base-metal deposits at the Otavi Land. The more expensive traditional methods necessary for the delineation of orebodies, such as pitting, trenching and drilling, are also discussed. Using a sequential approach, a possible exploration strategy is suggested, outlining the cost-effective use of remote sensing, geochemical and geophysical techniques. Standardisation in basic geological information is required for future successful explorations in the Damara-Katanga orogen, as well as attractive mining policies. In the event of their implementation, exploration perspectives are promising, specifically in terms of ore potential.
- Full Text:
- Date Issued: 1992
- Authors: Latorre, J J
- Date: 1992
- Subjects: Mining geology -- Research -- Africa , Copper ores -- Africa , Lead ores -- Africa , Zinc ores -- Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4946 , http://hdl.handle.net/10962/d1005558
- Description: The Damara-Katanga orogen in central-southern Africa represents an area of 1.73xl0⁶ sq. km. The region is considered one of the wealthiest metallogenic provinces in the world. Successful exploration for stratabound base-metal deposits has taken place at this particular area since the introduction of more organised methodology in the early 1920s. The genesis, location and distribution of the ore deposits are related to their tectonic settings. Geodynamic evolution of the orogen, which initially formed part of a complex Pan-African rift system, comprises the following stages rifting; downwarping, including spreading on the western portion; syn-orogeny and late-orogeny. Two major tectonic events in the history of the region have been identified: the Katangan (900-750 Ma) and the Damaran episodes (750-500 Ma). Timing of mineralisation of ore deposits has been related to the evolutionary stages of the orogen. Genetic models of the most productive deposits are briefly discussed in this dissertation. The sedimentological, geochemical, paleogeographic and structural features can be employed as geological guidelines for integrated exploration programmes. Discoveries of major deposits and prospects in the orogen are also summarised, focussing on the exploration methods employed. The cost-effective use of the exploration techniques includes the classical copper-lead-zinc soil sampling for residual soils such as those in the Copperbelt area. Airborne magnetics and electromagnetics and follow-up ground geophysics have proved successful in areas where the cover is transported in the search for shallow ore deposits such as the Matchless massive sulphides. Remote sensing, geochemical and geophysical techniques have been tried in covered areas of western Botswana. The lack of geological control makes this interpretation difficult. A detailed geological mapping and the use of geochemical and geophysical techniques has been used to delineate carbonate-hosted base-metal deposits at the Otavi Land. The more expensive traditional methods necessary for the delineation of orebodies, such as pitting, trenching and drilling, are also discussed. Using a sequential approach, a possible exploration strategy is suggested, outlining the cost-effective use of remote sensing, geochemical and geophysical techniques. Standardisation in basic geological information is required for future successful explorations in the Damara-Katanga orogen, as well as attractive mining policies. In the event of their implementation, exploration perspectives are promising, specifically in terms of ore potential.
- Full Text:
- Date Issued: 1992
The mandibular gland secretions and ovarial development of worker honeybees (Apis Mellifera) in the Eastern Cape Province of South Africa
- Authors: Reece, Sacha Louise
- Date: 2001
- Subjects: Honeybee -- South Africa -- Eastern Cape , Honeybee -- Behavior , Honeybee -- Physiology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5729 , http://hdl.handle.net/10962/d1005415 , Honeybee -- South Africa -- Eastern Cape , Honeybee -- Behavior , Honeybee -- Physiology
- Description: The Eastern Cape is an area in which Apis mellifera capensis, A. m. scutellata and their hybrid are known to naturally occur. I investigated the mandibular gland profiles and ovarial development of queenright workers from 4 localities. Their queens were then removed to determine how these aspects changed upon queen loss. In addition, drifted bees were analysed in the same way to determine how these factors changed once they had gained entry to a foreign hive. The queenright bees, form all 4 localities were found to have 9HDA as the most abundant of the 5 fatty acids measured and all localities had small percentages of 9ODA in their mandibular gland secretions. This resulted in relatively high queenright 9ODA:10HDA and 9HDA:10HDAA ratios. Despite this the percentage of bees with undeveloped ovaries was consistent with their queenright status. The mean values of these 2 ratios were significantly higher in the bees from East London and Cradock than those from Port Elizabeth. Steynsburg's bees were intermediate in this regard. Upon queen loss, the bees from all 4 localities had an increase in the percentage of 9ODA but the other compound changes in varying ways. East London's bees were the only ones not to become significantly more queen-like after queen loss. After 14 days without a queen, the mean values of these 2 ratios were much higher in the bees from Port Elizabeth than those from the other localities. Certain individuals from Port Elizabeth had values of these ratios that exceeded those found in A. m. capensis queens. Port Elizabeth was the only locality to display any surrogate queens and exhibited the highest increase in the number of bees with partially or fully developed ovaries. While certain individuals from the other localities had values of these ratios that exceeded these values reported in A. m. scutellata queens, Steynsburg's bees were the only ones that did increase in in terms of the number of bees with developed ovaries subsequent. The bees from Steynsburg were shown to suppress the mandibular gland and ovarial development of drifters from Port Elizabeth while bees from East London did not.
- Full Text:
- Date Issued: 2001
- Authors: Reece, Sacha Louise
- Date: 2001
- Subjects: Honeybee -- South Africa -- Eastern Cape , Honeybee -- Behavior , Honeybee -- Physiology
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5729 , http://hdl.handle.net/10962/d1005415 , Honeybee -- South Africa -- Eastern Cape , Honeybee -- Behavior , Honeybee -- Physiology
- Description: The Eastern Cape is an area in which Apis mellifera capensis, A. m. scutellata and their hybrid are known to naturally occur. I investigated the mandibular gland profiles and ovarial development of queenright workers from 4 localities. Their queens were then removed to determine how these aspects changed upon queen loss. In addition, drifted bees were analysed in the same way to determine how these factors changed once they had gained entry to a foreign hive. The queenright bees, form all 4 localities were found to have 9HDA as the most abundant of the 5 fatty acids measured and all localities had small percentages of 9ODA in their mandibular gland secretions. This resulted in relatively high queenright 9ODA:10HDA and 9HDA:10HDAA ratios. Despite this the percentage of bees with undeveloped ovaries was consistent with their queenright status. The mean values of these 2 ratios were significantly higher in the bees from East London and Cradock than those from Port Elizabeth. Steynsburg's bees were intermediate in this regard. Upon queen loss, the bees from all 4 localities had an increase in the percentage of 9ODA but the other compound changes in varying ways. East London's bees were the only ones not to become significantly more queen-like after queen loss. After 14 days without a queen, the mean values of these 2 ratios were much higher in the bees from Port Elizabeth than those from the other localities. Certain individuals from Port Elizabeth had values of these ratios that exceeded those found in A. m. capensis queens. Port Elizabeth was the only locality to display any surrogate queens and exhibited the highest increase in the number of bees with partially or fully developed ovaries. While certain individuals from the other localities had values of these ratios that exceeded these values reported in A. m. scutellata queens, Steynsburg's bees were the only ones that did increase in in terms of the number of bees with developed ovaries subsequent. The bees from Steynsburg were shown to suppress the mandibular gland and ovarial development of drifters from Port Elizabeth while bees from East London did not.
- Full Text:
- Date Issued: 2001
Selected physiological and perceptual responses of batsmen during a simulated one day international century : impact on performance
- Authors: Pote, Lee
- Date: 2013 , 2013-04-02
- Subjects: Cricket -- Batting , Sports -- Physiological aspects , Sports -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5097 , http://hdl.handle.net/10962/d1001650
- Description: Background: Very few studies have examined the demands of prolonged batting on physical, psychophysical and performance responses. Objective: The purpose of this study was therefore to determine the physiological and perceptual responses of batsmen scoring a simulated One Day International century. Furthermore, the impact that these responses had on batting performance were also measured. Methods: Seventeen male cricketers currently playing for Rhodes University or the country districts side, performed a simulated bating innings (BATEX©), typical of scoring a One Day international century. The BATEX© protocol consisted of six, five over stages (21 minutes each), with each stage matched to a specific phase of play where batsmen were encouraged to bat with the mindset of that phase. During stages one, three and five players ran at a “self-selected cruise pace” whereas during stages two, four and six players were required to run at maximum speed. At set intervals, selected physiological, perceptual and performance measures were recorded. Results: Most physiological responses increased and decreased accordingly with the low and high intensity stages with the exception of respiratory exchange ratio and core temperature responses. Mean physiological responses however, showed a progressive rise over time. Central ratings of perceived exertion increased as a function of intensity and duration. Sprint times got slower as the protocol progressed, while accuracy (impact accuracy) improved significantly (p<0.05) after stage one and then stabilised for the remainder of the protocol. Conclusion: The simulated batting protocol significantly impacted the physiological and perceptual responses over time. This was due to both the intensity and the duration of the work-bout. Furthermore, the increased physiological load placed on the batsmen significantly impacted the physical performance of the batsmen. An increase in sprint times (players getting slower) towards the end of the protocol may indicate the presence of physical fatigue. This physical fatigue did not however seem to impact the batsmen cognitively as accuracy improved after the first stage and then remained constant over time.
- Full Text:
- Date Issued: 2013
- Authors: Pote, Lee
- Date: 2013 , 2013-04-02
- Subjects: Cricket -- Batting , Sports -- Physiological aspects , Sports -- Psychological aspects
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5097 , http://hdl.handle.net/10962/d1001650
- Description: Background: Very few studies have examined the demands of prolonged batting on physical, psychophysical and performance responses. Objective: The purpose of this study was therefore to determine the physiological and perceptual responses of batsmen scoring a simulated One Day International century. Furthermore, the impact that these responses had on batting performance were also measured. Methods: Seventeen male cricketers currently playing for Rhodes University or the country districts side, performed a simulated bating innings (BATEX©), typical of scoring a One Day international century. The BATEX© protocol consisted of six, five over stages (21 minutes each), with each stage matched to a specific phase of play where batsmen were encouraged to bat with the mindset of that phase. During stages one, three and five players ran at a “self-selected cruise pace” whereas during stages two, four and six players were required to run at maximum speed. At set intervals, selected physiological, perceptual and performance measures were recorded. Results: Most physiological responses increased and decreased accordingly with the low and high intensity stages with the exception of respiratory exchange ratio and core temperature responses. Mean physiological responses however, showed a progressive rise over time. Central ratings of perceived exertion increased as a function of intensity and duration. Sprint times got slower as the protocol progressed, while accuracy (impact accuracy) improved significantly (p<0.05) after stage one and then stabilised for the remainder of the protocol. Conclusion: The simulated batting protocol significantly impacted the physiological and perceptual responses over time. This was due to both the intensity and the duration of the work-bout. Furthermore, the increased physiological load placed on the batsmen significantly impacted the physical performance of the batsmen. An increase in sprint times (players getting slower) towards the end of the protocol may indicate the presence of physical fatigue. This physical fatigue did not however seem to impact the batsmen cognitively as accuracy improved after the first stage and then remained constant over time.
- Full Text:
- Date Issued: 2013
The sedimentology and palaeoenvironmental significance of vlei sediments on the Winterberg range, South Africa
- Authors: Dewey, Felicity Joy
- Date: 1989
- Subjects: Geology, Stratigraphic -- Holocene Sedimentology Sediments (Geology) -- South Africa -- Eastern Cape -- Winterberg range Geology, Stratigraphic -- Pleistocene Paleoecology -- South Africa -- Eastern Cape -- Winterberg range
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4797 , http://hdl.handle.net/10962/d1001897
- Description: Palaeoenvironmental reconstruction of the late Pleistocene and Holocene geological periods for central and southern Africa has been hampered by the erratic distribution of suitable sites, incomplete and inaccurately dated sequences and the limited nature of published data. One geomorphological feature which has supplied valuable evidence for fluctuations in past environmental conditions, is the vlei or dambo. The type-site of these waterlogged features is in south central Africa, but similar features have been described on other continents. The clastic and organic sediments contained within these features are affected by, and therefore reflect to some degree, the environment under which they were formed. The characteristics of the sediments supply information as to their transport and mechanisms of deposition. From these processes, the environmental conditions at the time of vlei formation can be inferred. The environmental history of the Eastern Cape region has been considerably neglected, and is far less well understood than other countries such as Malawi, Zambia and Zimbabwe. A study site in the Winterberg Range (Eastern Cape) was selected which permitted the comparison of two vleis, the objective being to establish an accurate late Pleistocene sediment chronology for the entire plateau area. Radiocarbon dates from organic layers indicate that these sediments span the last 12 000 years BP, suggesting that organic accumulation at this site began at roughly the same time as at sites further afield. The vlei sediments are analysed in terms of their morphology, particle slze distribution, and other physical and chemical characteristics. These data facilitate the construction of detailed stratigraphic diagrams and a chronological summary of sediment accumulation, from which the period and governing processes of vlei development under changing environments may be described. It is found that the Winterberg vleis contain sediments which respond to changes in the prevailing environment. This makes these sediments useful indices from which to trace such changes during the late Pleistocene and Holocene times. These features are found to be similar in many respects to those described elsewhere in Southern Africa. The study attempts to provide greater understanding of contemporary vlei processes and emphasises the necessity of their preservation, as finite and valuable resources, by future generations
- Full Text:
- Date Issued: 1989
- Authors: Dewey, Felicity Joy
- Date: 1989
- Subjects: Geology, Stratigraphic -- Holocene Sedimentology Sediments (Geology) -- South Africa -- Eastern Cape -- Winterberg range Geology, Stratigraphic -- Pleistocene Paleoecology -- South Africa -- Eastern Cape -- Winterberg range
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4797 , http://hdl.handle.net/10962/d1001897
- Description: Palaeoenvironmental reconstruction of the late Pleistocene and Holocene geological periods for central and southern Africa has been hampered by the erratic distribution of suitable sites, incomplete and inaccurately dated sequences and the limited nature of published data. One geomorphological feature which has supplied valuable evidence for fluctuations in past environmental conditions, is the vlei or dambo. The type-site of these waterlogged features is in south central Africa, but similar features have been described on other continents. The clastic and organic sediments contained within these features are affected by, and therefore reflect to some degree, the environment under which they were formed. The characteristics of the sediments supply information as to their transport and mechanisms of deposition. From these processes, the environmental conditions at the time of vlei formation can be inferred. The environmental history of the Eastern Cape region has been considerably neglected, and is far less well understood than other countries such as Malawi, Zambia and Zimbabwe. A study site in the Winterberg Range (Eastern Cape) was selected which permitted the comparison of two vleis, the objective being to establish an accurate late Pleistocene sediment chronology for the entire plateau area. Radiocarbon dates from organic layers indicate that these sediments span the last 12 000 years BP, suggesting that organic accumulation at this site began at roughly the same time as at sites further afield. The vlei sediments are analysed in terms of their morphology, particle slze distribution, and other physical and chemical characteristics. These data facilitate the construction of detailed stratigraphic diagrams and a chronological summary of sediment accumulation, from which the period and governing processes of vlei development under changing environments may be described. It is found that the Winterberg vleis contain sediments which respond to changes in the prevailing environment. This makes these sediments useful indices from which to trace such changes during the late Pleistocene and Holocene times. These features are found to be similar in many respects to those described elsewhere in Southern Africa. The study attempts to provide greater understanding of contemporary vlei processes and emphasises the necessity of their preservation, as finite and valuable resources, by future generations
- Full Text:
- Date Issued: 1989
A study of fuzzy sets and systems with applications to group theory and decision making
- Authors: Gideon, Frednard
- Date: 2006
- Subjects: Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5417 , http://hdl.handle.net/10962/d1005231 , Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Description: In this study we apply the knowledge of fuzzy sets to group structures and also to decision-making implications. We study fuzzy subgroups of finite abelian groups. We set G = Z[subscript p[superscript n]] + Z[subscript q[superscript m]]. The classification of fuzzy subgroups of G using equivalence classes is introduced. First, we present equivalence relations on fuzzy subsets of X, and then extend it to the study of equivalence relations of fuzzy subgroups of a group G. This is then followed by the notion of flags and keychains projected as tools for enumerating fuzzy subgroups of G. In addition to this, we use linear ordering of the lattice of subgroups to characterize the maximal chains of G. Then we narrow the gap between group theory and decision-making using relations. Finally, a theory of the decision-making process in a fuzzy environment leads to a fuzzy version of capital budgeting. We define the goal, constraints and decision and show how they conflict with each other using membership function implications. We establish sets of intervals for projecting decision boundaries in general. We use the knowledge of triangular fuzzy numbers which are restricted field of fuzzy logic to evaluate investment projections.
- Full Text:
- Date Issued: 2006
- Authors: Gideon, Frednard
- Date: 2006
- Subjects: Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:5417 , http://hdl.handle.net/10962/d1005231 , Fuzzy sets , Fuzzy systems , Abelian groups , Decision making
- Description: In this study we apply the knowledge of fuzzy sets to group structures and also to decision-making implications. We study fuzzy subgroups of finite abelian groups. We set G = Z[subscript p[superscript n]] + Z[subscript q[superscript m]]. The classification of fuzzy subgroups of G using equivalence classes is introduced. First, we present equivalence relations on fuzzy subsets of X, and then extend it to the study of equivalence relations of fuzzy subgroups of a group G. This is then followed by the notion of flags and keychains projected as tools for enumerating fuzzy subgroups of G. In addition to this, we use linear ordering of the lattice of subgroups to characterize the maximal chains of G. Then we narrow the gap between group theory and decision-making using relations. Finally, a theory of the decision-making process in a fuzzy environment leads to a fuzzy version of capital budgeting. We define the goal, constraints and decision and show how they conflict with each other using membership function implications. We establish sets of intervals for projecting decision boundaries in general. We use the knowledge of triangular fuzzy numbers which are restricted field of fuzzy logic to evaluate investment projections.
- Full Text:
- Date Issued: 2006
Initiating biological control for Nymphaea mexicana zuccarini (Nymphaeaceae) in South Africa
- Authors: Reid, Megan
- Date: 2020
- Subjects: Nymphaea mexicana zuccarini -- Biological control -- South Africa , Nymphaeaceae -- Biological control -- South Africa , Invasive plants -- Biological control -- South Africa
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/144510 , vital:38352
- Description: Nymphaea mexicana Zuccarini (Nymphaeaceae) is an aquatic plant originating from south-eastern USA that is becoming increasingly invasive in South Africa as other invasive aquatic plants are being managed successfully through biological control. Mechanical and chemical control of aquatic weeds is expensive, damaging to the environment, and only effective in the short term, so biological control is more desirable as a management strategy for N. mexicana. The biological control of invasive alien plants requires that agents are host specific so that non-target risks are mitigated. For success to be achieved, it is important to ensure that the genetic structure of invasive populations is clarified so that agents can be collected from populations in the native range that match genetically to populations in the invasive range. This is especially important in cases where the morphology of invasive alien plants does not reflect genetic differences between populations. A previous study of the genetic structure of the invasive populations of N. mexicana in South Africa suggests the presence of hybrid forms of the plant in South Africa, with only one of these populations matching with samples from the native range. However, the study only used samples from two sites in the native range using amplified fragment length polymorphisms (AFLPs), so it was necessary to conduct further genetic analyses using samples from more sites in the native range. Hence, the first aim of this study was to develop a better understanding of the genetic structure of N. mexicana populations in the native and invaded range. Genetic samples were collected from sites in the native range during field surveys for potential biological control agents, and inter-simple sequence repeats (ISSRs) were used to compare the genetic structure of invasive and native populations of N. mexicana in South Africa. The results from these analyses suggest that seven of the 14 investigated invasive populations of N. mexicana in South Africa are genetically similar to populations in the native range, while the remaining seven populations are likely to be hybrid forms of the plant. This knowledge will be useful to target populations for biological control and highlights the need for further genetic analyses to determine the parentage of these hybrids so that biological control efforts are more likely to be successful. The initiation of a biological control programme requires that a series of steps are taken in order to maximise the likelihood that this form of intervention will be successful. The first few steps include: identification of the target weed and its genetic structure; exploration in the native range for potential biological control agents; and prioritisation of these agents based on factors such as climatic and genetic compatibility, feeding damage, abundance, and likely host range. Hence, the second aim of this study was to conduct surveys for potential biological control agents in the native range of N. mexicana, and to prioritise these agents. Field surveys were conducted between August and October in 2018 at 17 sites in Florida, Louisiana, and Texas, USA. Sites were selected based on climatic similarity of native sites compared to invasive sites by use of MaxEnt modelling. Native N. mexicana plants were searched for natural enemies, and these were prioritised based on feeding damage, abundance, incidence, and observations of field host range. Two species were prioritised: Bagous americanus LeConte (Coleoptera: Curculionidae) and Megamelus toddi Beamer (Hemiptera: Delphacidae). These species will be imported into quarantine facilities at Rhodes University for host specificity tests to be conducted. Understanding the factors that contribute to the successful establishment of biological control agents is important to improve the efficiency and reduce the costs incurred during the initiation of biological control programmes. Acquiring knowledge of the factors that predict the efficacy of biological control agents is similarly important, and these factors are discussed in the last chapter of this study. The challenges of the biological control of hybrids are also considered, and recommendations are made for the control of N. mexicana and other plants in South Africa.
- Full Text:
- Date Issued: 2020
- Authors: Reid, Megan
- Date: 2020
- Subjects: Nymphaea mexicana zuccarini -- Biological control -- South Africa , Nymphaeaceae -- Biological control -- South Africa , Invasive plants -- Biological control -- South Africa
- Language: English
- Type: text , Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10962/144510 , vital:38352
- Description: Nymphaea mexicana Zuccarini (Nymphaeaceae) is an aquatic plant originating from south-eastern USA that is becoming increasingly invasive in South Africa as other invasive aquatic plants are being managed successfully through biological control. Mechanical and chemical control of aquatic weeds is expensive, damaging to the environment, and only effective in the short term, so biological control is more desirable as a management strategy for N. mexicana. The biological control of invasive alien plants requires that agents are host specific so that non-target risks are mitigated. For success to be achieved, it is important to ensure that the genetic structure of invasive populations is clarified so that agents can be collected from populations in the native range that match genetically to populations in the invasive range. This is especially important in cases where the morphology of invasive alien plants does not reflect genetic differences between populations. A previous study of the genetic structure of the invasive populations of N. mexicana in South Africa suggests the presence of hybrid forms of the plant in South Africa, with only one of these populations matching with samples from the native range. However, the study only used samples from two sites in the native range using amplified fragment length polymorphisms (AFLPs), so it was necessary to conduct further genetic analyses using samples from more sites in the native range. Hence, the first aim of this study was to develop a better understanding of the genetic structure of N. mexicana populations in the native and invaded range. Genetic samples were collected from sites in the native range during field surveys for potential biological control agents, and inter-simple sequence repeats (ISSRs) were used to compare the genetic structure of invasive and native populations of N. mexicana in South Africa. The results from these analyses suggest that seven of the 14 investigated invasive populations of N. mexicana in South Africa are genetically similar to populations in the native range, while the remaining seven populations are likely to be hybrid forms of the plant. This knowledge will be useful to target populations for biological control and highlights the need for further genetic analyses to determine the parentage of these hybrids so that biological control efforts are more likely to be successful. The initiation of a biological control programme requires that a series of steps are taken in order to maximise the likelihood that this form of intervention will be successful. The first few steps include: identification of the target weed and its genetic structure; exploration in the native range for potential biological control agents; and prioritisation of these agents based on factors such as climatic and genetic compatibility, feeding damage, abundance, and likely host range. Hence, the second aim of this study was to conduct surveys for potential biological control agents in the native range of N. mexicana, and to prioritise these agents. Field surveys were conducted between August and October in 2018 at 17 sites in Florida, Louisiana, and Texas, USA. Sites were selected based on climatic similarity of native sites compared to invasive sites by use of MaxEnt modelling. Native N. mexicana plants were searched for natural enemies, and these were prioritised based on feeding damage, abundance, incidence, and observations of field host range. Two species were prioritised: Bagous americanus LeConte (Coleoptera: Curculionidae) and Megamelus toddi Beamer (Hemiptera: Delphacidae). These species will be imported into quarantine facilities at Rhodes University for host specificity tests to be conducted. Understanding the factors that contribute to the successful establishment of biological control agents is important to improve the efficiency and reduce the costs incurred during the initiation of biological control programmes. Acquiring knowledge of the factors that predict the efficacy of biological control agents is similarly important, and these factors are discussed in the last chapter of this study. The challenges of the biological control of hybrids are also considered, and recommendations are made for the control of N. mexicana and other plants in South Africa.
- Full Text:
- Date Issued: 2020
A study of the coordination behaviour of the lanthanide series with oxygen-donor ligands
- Authors: Kuhn, Kirsti
- Date: 2012
- Subjects: Chemical elements , Chemical reactions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10394 , http://hdl.handle.net/10948/d1009533 , Chemical elements , Chemical reactions
- Description: The reactions between the lanthanide nitrate salts and the ligand triphenylphosphine oxide (TPPO) gave rise to nine-coordinated complexes of the nature Ln(TPPO)3(NO3)3, for Ln = La – Dy, Er, Tm, in which the Ln(III) centre is coordinated to three phosphoryl oxygen atoms and three bidentate nitrate ligands. Generally, the geometry can be described as being mer-octahedral, where the nitrate ligands are considered as monoatomic species. The product of the reaction between Yb(NO3)3·5H2O and TPPO, however, was a highly symmetrical eight-coordinated complex, in which the Yb(III) centre was coordinated to two bidentate nitrate groups and four TPPO molecules. The geometry in this case is best described as being trans-octahedral, with the two nitrate ligands coordinated practically perpendicular to one another. The complexes isolated from the reactions of lanthanide nitrate salts with the ligand bis(pentamethylene)urea (PMU) had the general formula Ln(PMU)3(NO3)3, where Ln = La – Dy, Yb, Lu. The complexes were found to be nine-coordinated with distorted trigonal prismatic geometry, in which the one base of the prism is composed of the oxygen atoms of the three PMU ligands and the other base is made up by one oxygen atom from each of the bidentate nitrate groups. The second oxygen atoms of each of the nitrate groups protrude upward, occupying capping positions. The reactions of the La and Pr nitrate salts with the ligand 2,2’-dipyridyl-N,N’-dioxide (DPDO) produced two novel complexes of the nature [Ln(DPDO)(H2O)2(NO3)3]. These complexes are remarkable in that their crystal structures reveal the Ln(III) centres to be ten-coordinated. The geometry around the Ln(III) centres was complex, due to the presence of a seven-membered chelate ring, formed by the bidentate coordination of the oxygen atoms from the DPDO ligands to the metal centres. The chelate ring did not lie in a single plane, but was twisted at the pyridyl bridgeheads to lie above and below the coordination plane.
- Full Text:
- Date Issued: 2012
- Authors: Kuhn, Kirsti
- Date: 2012
- Subjects: Chemical elements , Chemical reactions
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:10394 , http://hdl.handle.net/10948/d1009533 , Chemical elements , Chemical reactions
- Description: The reactions between the lanthanide nitrate salts and the ligand triphenylphosphine oxide (TPPO) gave rise to nine-coordinated complexes of the nature Ln(TPPO)3(NO3)3, for Ln = La – Dy, Er, Tm, in which the Ln(III) centre is coordinated to three phosphoryl oxygen atoms and three bidentate nitrate ligands. Generally, the geometry can be described as being mer-octahedral, where the nitrate ligands are considered as monoatomic species. The product of the reaction between Yb(NO3)3·5H2O and TPPO, however, was a highly symmetrical eight-coordinated complex, in which the Yb(III) centre was coordinated to two bidentate nitrate groups and four TPPO molecules. The geometry in this case is best described as being trans-octahedral, with the two nitrate ligands coordinated practically perpendicular to one another. The complexes isolated from the reactions of lanthanide nitrate salts with the ligand bis(pentamethylene)urea (PMU) had the general formula Ln(PMU)3(NO3)3, where Ln = La – Dy, Yb, Lu. The complexes were found to be nine-coordinated with distorted trigonal prismatic geometry, in which the one base of the prism is composed of the oxygen atoms of the three PMU ligands and the other base is made up by one oxygen atom from each of the bidentate nitrate groups. The second oxygen atoms of each of the nitrate groups protrude upward, occupying capping positions. The reactions of the La and Pr nitrate salts with the ligand 2,2’-dipyridyl-N,N’-dioxide (DPDO) produced two novel complexes of the nature [Ln(DPDO)(H2O)2(NO3)3]. These complexes are remarkable in that their crystal structures reveal the Ln(III) centres to be ten-coordinated. The geometry around the Ln(III) centres was complex, due to the presence of a seven-membered chelate ring, formed by the bidentate coordination of the oxygen atoms from the DPDO ligands to the metal centres. The chelate ring did not lie in a single plane, but was twisted at the pyridyl bridgeheads to lie above and below the coordination plane.
- Full Text:
- Date Issued: 2012
Molecular and biochemical analysis of the diet of the black rhinoceros
- Authors: Kgopa, Ananias Hodi
- Date: 2009 , 2013-07-15
- Subjects: Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4064 , http://hdl.handle.net/10962/d1004721 , Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Description: The black rhinoceros, Diceros bicornis, is listed as critically endangered. The black rhinoceros population in the Great Fish River Reserve (GFRR) has increased steadily to a current estimate of one hundred animals since the re-introduction of four animals in 1986. In an effort to contribute to the effective conservation and management of this species, dietary composition was studied in the medium Portulcaria thicket vegetation of the GFRR. This study used a molecular approach to determine the diet of the black rhinoceros of the GFRR by sequencing the ribulose bisphosphate carboxylase large subunit (rbcL) gene in plants and dung. Twenty-three plant species were collected from the reserve, and 802 bp of the rbcL gene were sequenced. These plant sequences were used as a reference database for the identification of plant sequences generated from black rhinoceros dung. Initial studies investigated the amplification, cloning and sequencing of DNA extracted from the dung samples which indicated the viability of the molecular approach. Thereafter, dung generated rbcL DNA was analyzed by GS FLX sequencing. Of the plant sequences identified by comparison to the GenBank database, Carissa bispinosa was the most prevalent. The study further characterized the antioxidant activities and phenolic content of plants eaten by the black rhinoceros using four different assays. Phyllanthus verrucosus, Putterlickia pyracantha, Maytenus capitata, Euclea undulata and Ozoroa mucrunata consistently had high antioxidant activities when assayed against 2,2-azinobis (3-ethyl benzothiazolium-6-sulfonic acid) (ABTSʹ⁺), 2,2-diphenyl-1-picrylhydrazyl (DPPHʹ), and ferric reducing antioxidant potentials (FRAP) and phenolic content when evaluated using the Folin-Ciocalteu assay. The majority of plants investigated showed low antioxidant potentials and low phenolic content. The extent to which antioxidants influenced the browse selection by the black rhinoceros remains inconclusive.
- Full Text:
- Date Issued: 2009
- Authors: Kgopa, Ananias Hodi
- Date: 2009 , 2013-07-15
- Subjects: Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: vital:4064 , http://hdl.handle.net/10962/d1004721 , Black rhinoceros -- South Africa -- Eastern Cape , Browse (Animal food) -- South Africa -- Eastern Cape -- Analysis , Black rhinoceros -- Manure -- Analysis , Phenols , Antioxidants , Plant ecology -- South Africa -- Eastern Cape
- Description: The black rhinoceros, Diceros bicornis, is listed as critically endangered. The black rhinoceros population in the Great Fish River Reserve (GFRR) has increased steadily to a current estimate of one hundred animals since the re-introduction of four animals in 1986. In an effort to contribute to the effective conservation and management of this species, dietary composition was studied in the medium Portulcaria thicket vegetation of the GFRR. This study used a molecular approach to determine the diet of the black rhinoceros of the GFRR by sequencing the ribulose bisphosphate carboxylase large subunit (rbcL) gene in plants and dung. Twenty-three plant species were collected from the reserve, and 802 bp of the rbcL gene were sequenced. These plant sequences were used as a reference database for the identification of plant sequences generated from black rhinoceros dung. Initial studies investigated the amplification, cloning and sequencing of DNA extracted from the dung samples which indicated the viability of the molecular approach. Thereafter, dung generated rbcL DNA was analyzed by GS FLX sequencing. Of the plant sequences identified by comparison to the GenBank database, Carissa bispinosa was the most prevalent. The study further characterized the antioxidant activities and phenolic content of plants eaten by the black rhinoceros using four different assays. Phyllanthus verrucosus, Putterlickia pyracantha, Maytenus capitata, Euclea undulata and Ozoroa mucrunata consistently had high antioxidant activities when assayed against 2,2-azinobis (3-ethyl benzothiazolium-6-sulfonic acid) (ABTSʹ⁺), 2,2-diphenyl-1-picrylhydrazyl (DPPHʹ), and ferric reducing antioxidant potentials (FRAP) and phenolic content when evaluated using the Folin-Ciocalteu assay. The majority of plants investigated showed low antioxidant potentials and low phenolic content. The extent to which antioxidants influenced the browse selection by the black rhinoceros remains inconclusive.
- Full Text:
- Date Issued: 2009
Risk analysis and management systems in South African construction project management practices
- Authors: Cook, Iain Murray
- Date: 2016
- Subjects: Construction projects -- Management , Construction industry -- Risk management , Project management -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/3469 , vital:20433
- Description: Risk management (RM) should be seen as one of the most important functions in the South African built environment. Without the effective management of the risks associated with the industry, the noble vision of a sector that is efficient, profitable, and sustainable cannot be achieved. By embracing tried and tested policies that successfully mitigate risk, industry stakeholders will achieve many project successes, and will outlast any competitors that choose to ignore, or are ignorant of the fact, that the negative impact risk has on projects is inversely proportional to the level of RM employed. Construction Project Management (CPM) practices, realising that there are excellent business opportunities across South Africa’s borders, and faced with a competitive South African market, are engaging with developers and government entities involved in cross border projects in the hope of securing these potentially lucrative African projects. With this move into Africa comes increased uncertainty and risk for these CPM practices, and other project stakeholders. Similarly, CPM practices that have made the strategic decision to remain operational only within South Africa’s borders, are faced with a competitive and complex built environment and industry, made increasingly challenging by a weakening economy, exacerbated by industrial strikes, infrastructure deficiencies and a decrease in industry skill levels. This study reports on Project Managers’ (PMs’) perceptions of project failures and inefficiencies resulting from inadequate RM on projects, including the RM methodologies currently being employed. The study focused on perceptions of PMs who operate within South Africa’s borders, PMs that operate across border into other African countries, as well as PMs who operate exclusively within South Africa’s built environment framework. A study was undertaken incorporating qualitative methodologies via a normative survey. The survey was split into three main phases. Phase one employed the use of a pilot survey executed with the objective of further investigating the main sub-problems to gain more insight into the related issues and challenges. For the pilot survey, PMs were selected based on their engagement in CPM activities within South Africa as well as across South Africa’s borders into other African countries. Phase two of the main survey, with the sample stratum being the Association of Construction Project Managers (ACPM), was aimed at PMs within the ACPM who have engaged, or are engaging, in CPM activities both within South Africa’s borders as well as across South Africa’s borders into other African countries. Phase 3 of the main survey, with the sample stratum being the ACPM, was aimed at PMs within the ACPM who have engaged, or are engaging, in CPM activities within South Africa’s borders only and have not engaged in cross border activities. Survey findings identified the commercial sector and value of the projects undertaken by the practices, the level of risk associated with different client typologies, the link between inadequate RM and project inefficiency and failure, and the importance of RM on projects. Findings also identified that RM methodologies are employed by CPM practices, and that CPM practices generally endeavour to create a culture of risk awareness amongst employees. Further findings indicated that CPM practices may not always understand the risks associated with new industry sectors, regions or countries that they are considering operating within, and that that there is room for improvement regarding the effectiveness of current RM systems. Survey findings also indicated that risk is not always transferred to the correct project stakeholder most suited to managing the risk, and CPM practices are not always able to accurately quantify the costs associated with project risk. Furthermore, it was identified that CPM practices do not always undertaken risk assessments (RAs) at the correct project stage resulting in inadequate risk contingencies allowances, regular risk reviews are not always undertaken for projects, project pre-mortems are seen as valuable tools by CPM practices as a method to reduce future risk, and project post-mortems relative to ‘lessons learnt’ are not always undertaken. Conclusions outline the link between effective RM, project inefficiencies and project failure, as well as the increase or decrease in risk relative to ineffective or effective use of risk identification and management methodologies for time, cost, and quality factors respectively. Conclusions also outline the fact that although CPM practices generally understand the link between RM and project success, they are not always able to fully comprehend the risks associated with new industry sectors, regions or cross border countries. This indicates that without the adequate identification of risk, the RM process or steps that follow the qualitative risk identification process will have little or no value. This is indicative of the requirement for professional associations to consolidate risk data for industry activities with the aim of improving the level of RM industry wide. Recommendations highlight the importance of the compiling of sector specific risk registers, compiled by the South African Council for the Project and Construction Management Professions (SACPCMP) with registered member input, made available to all PMs via the SACPCMPs online database. Further recommendations include: the engendering, by senior management of CPM practices; a healthy ‘risk aware’ culture, by promoting RM practices aligned with best practice methodologies; the implementation of well balanced and formal RM systems throughout the CPM practice, with the aim of achieving effective RM without overburdening PMs with unnecessary documentation or ‘paperwork’; the attendance of risk conferences and workshops by all CPM practices, aimed at specifically identifying challenges that exist with RM and methods that can be employed to improve the status quo; the attendance of formal risk training courses, by all CPM practices, aimed at improving the knowledge base of PMs relative to effective RM, and the appointment of risk professionals, driven by the monetary value and risk levels of the project, to undertake the RM process and unburden PMs from the task, allowing PMs to concentrate on the other project knowledge areas.
- Full Text:
- Date Issued: 2016
- Authors: Cook, Iain Murray
- Date: 2016
- Subjects: Construction projects -- Management , Construction industry -- Risk management , Project management -- South Africa
- Language: English
- Type: Thesis , Masters , MSc
- Identifier: http://hdl.handle.net/10948/3469 , vital:20433
- Description: Risk management (RM) should be seen as one of the most important functions in the South African built environment. Without the effective management of the risks associated with the industry, the noble vision of a sector that is efficient, profitable, and sustainable cannot be achieved. By embracing tried and tested policies that successfully mitigate risk, industry stakeholders will achieve many project successes, and will outlast any competitors that choose to ignore, or are ignorant of the fact, that the negative impact risk has on projects is inversely proportional to the level of RM employed. Construction Project Management (CPM) practices, realising that there are excellent business opportunities across South Africa’s borders, and faced with a competitive South African market, are engaging with developers and government entities involved in cross border projects in the hope of securing these potentially lucrative African projects. With this move into Africa comes increased uncertainty and risk for these CPM practices, and other project stakeholders. Similarly, CPM practices that have made the strategic decision to remain operational only within South Africa’s borders, are faced with a competitive and complex built environment and industry, made increasingly challenging by a weakening economy, exacerbated by industrial strikes, infrastructure deficiencies and a decrease in industry skill levels. This study reports on Project Managers’ (PMs’) perceptions of project failures and inefficiencies resulting from inadequate RM on projects, including the RM methodologies currently being employed. The study focused on perceptions of PMs who operate within South Africa’s borders, PMs that operate across border into other African countries, as well as PMs who operate exclusively within South Africa’s built environment framework. A study was undertaken incorporating qualitative methodologies via a normative survey. The survey was split into three main phases. Phase one employed the use of a pilot survey executed with the objective of further investigating the main sub-problems to gain more insight into the related issues and challenges. For the pilot survey, PMs were selected based on their engagement in CPM activities within South Africa as well as across South Africa’s borders into other African countries. Phase two of the main survey, with the sample stratum being the Association of Construction Project Managers (ACPM), was aimed at PMs within the ACPM who have engaged, or are engaging, in CPM activities both within South Africa’s borders as well as across South Africa’s borders into other African countries. Phase 3 of the main survey, with the sample stratum being the ACPM, was aimed at PMs within the ACPM who have engaged, or are engaging, in CPM activities within South Africa’s borders only and have not engaged in cross border activities. Survey findings identified the commercial sector and value of the projects undertaken by the practices, the level of risk associated with different client typologies, the link between inadequate RM and project inefficiency and failure, and the importance of RM on projects. Findings also identified that RM methodologies are employed by CPM practices, and that CPM practices generally endeavour to create a culture of risk awareness amongst employees. Further findings indicated that CPM practices may not always understand the risks associated with new industry sectors, regions or countries that they are considering operating within, and that that there is room for improvement regarding the effectiveness of current RM systems. Survey findings also indicated that risk is not always transferred to the correct project stakeholder most suited to managing the risk, and CPM practices are not always able to accurately quantify the costs associated with project risk. Furthermore, it was identified that CPM practices do not always undertaken risk assessments (RAs) at the correct project stage resulting in inadequate risk contingencies allowances, regular risk reviews are not always undertaken for projects, project pre-mortems are seen as valuable tools by CPM practices as a method to reduce future risk, and project post-mortems relative to ‘lessons learnt’ are not always undertaken. Conclusions outline the link between effective RM, project inefficiencies and project failure, as well as the increase or decrease in risk relative to ineffective or effective use of risk identification and management methodologies for time, cost, and quality factors respectively. Conclusions also outline the fact that although CPM practices generally understand the link between RM and project success, they are not always able to fully comprehend the risks associated with new industry sectors, regions or cross border countries. This indicates that without the adequate identification of risk, the RM process or steps that follow the qualitative risk identification process will have little or no value. This is indicative of the requirement for professional associations to consolidate risk data for industry activities with the aim of improving the level of RM industry wide. Recommendations highlight the importance of the compiling of sector specific risk registers, compiled by the South African Council for the Project and Construction Management Professions (SACPCMP) with registered member input, made available to all PMs via the SACPCMPs online database. Further recommendations include: the engendering, by senior management of CPM practices; a healthy ‘risk aware’ culture, by promoting RM practices aligned with best practice methodologies; the implementation of well balanced and formal RM systems throughout the CPM practice, with the aim of achieving effective RM without overburdening PMs with unnecessary documentation or ‘paperwork’; the attendance of risk conferences and workshops by all CPM practices, aimed at specifically identifying challenges that exist with RM and methods that can be employed to improve the status quo; the attendance of formal risk training courses, by all CPM practices, aimed at improving the knowledge base of PMs relative to effective RM, and the appointment of risk professionals, driven by the monetary value and risk levels of the project, to undertake the RM process and unburden PMs from the task, allowing PMs to concentrate on the other project knowledge areas.
- Full Text:
- Date Issued: 2016