Vho Madevha
- Kruger, Jaco (Recorded by), Phophi, George (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Phophi, George (Performer) , Composer unknown
- Subjects: Malavuhe , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Mbila , Tshizambi , Malombo song , Trance dance song
- Type: Music , Sound
- Identifier: vital:16039 , JKC09a-04 , http://hdl.handle.net/10962/d1009228 , Tape number: JKC09 , Original tape number: 9 , Track number: 04
- Description: Traditional Venda trance dance song accompanied by the tshizambi friction musical bow , For further details refer to Jaco Kruger recording card: 107
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Phophi, George (Performer) , Composer unknown
- Subjects: Malavuhe , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Mbila , Tshizambi , Malombo song , Trance dance song
- Type: Music , Sound
- Identifier: vital:16039 , JKC09a-04 , http://hdl.handle.net/10962/d1009228 , Tape number: JKC09 , Original tape number: 9 , Track number: 04
- Description: Traditional Venda trance dance song accompanied by the tshizambi friction musical bow , For further details refer to Jaco Kruger recording card: 107
- Full Text: false
Plan of a portion of the Kei Garip or Great Orange River, extending from Eis to Pella Mission Station and forming the Northern frontier of the Colony : constructet from observations made during a journey from Little Namaqualand to Kuruman in October 1856...
- Authors: Moffat, Robert, 1827-1862
- Date: 1857
- Subjects: Cape of Good Hope (South Africa) -- Maps Maps , Namaqualand (South Africa) -- Maps Maps , Orange River -- Maps Maps , South Africa
- Language: English
- Type: cartographic , map
- Identifier: http://hdl.handle.net/10962/55456 , vital:26701 , Cory Library for Humanities Research, Rhodes University Library, Grahamstown, South Africa MP130 , MP131
- Description: Respectfully presented to the Colonial Government with a memoir signed by R. Moffat Jun. .. Kuruman, Jan., 1857.
- Full Text: false
- Date Issued: 1857
- Authors: Moffat, Robert, 1827-1862
- Date: 1857
- Subjects: Cape of Good Hope (South Africa) -- Maps Maps , Namaqualand (South Africa) -- Maps Maps , Orange River -- Maps Maps , South Africa
- Language: English
- Type: cartographic , map
- Identifier: http://hdl.handle.net/10962/55456 , vital:26701 , Cory Library for Humanities Research, Rhodes University Library, Grahamstown, South Africa MP130 , MP131
- Description: Respectfully presented to the Colonial Government with a memoir signed by R. Moffat Jun. .. Kuruman, Jan., 1857.
- Full Text: false
- Date Issued: 1857
Joni
- Botha, Karika (Recorded by), Sesotho children (Performer), Composer unknown
- Authors: Botha, Karika (Recorded by) , Sesotho children (Performer) , Composer unknown
- Subjects: Shongoane village , Lephalale , Transvaal (Limpopo) , South Africa , Indigenous music , Children's song , Clapping
- Type: Music , Sound
- Identifier: vital:16084 , JKC17b-19 , http://hdl.handle.net/10962/d1009273 , Tape number: JKC17 , Original tape number: 17 , Track number: 19
- Description: Children's song with clapping accompaniment about Joni who has taken the cows for grazing , Refer to last page of Jaco Kruger recording card book II
- Full Text: false
- Authors: Botha, Karika (Recorded by) , Sesotho children (Performer) , Composer unknown
- Subjects: Shongoane village , Lephalale , Transvaal (Limpopo) , South Africa , Indigenous music , Children's song , Clapping
- Type: Music , Sound
- Identifier: vital:16084 , JKC17b-19 , http://hdl.handle.net/10962/d1009273 , Tape number: JKC17 , Original tape number: 17 , Track number: 19
- Description: Children's song with clapping accompaniment about Joni who has taken the cows for grazing , Refer to last page of Jaco Kruger recording card book II
- Full Text: false
Tshimphi ndi dobe Part I
- Kruger, Jaco (Recorded by), Richard Shonisani and Ephraim Randima (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Richard Shonisani and Ephraim Randima (Performer) , Composer unknown
- Subjects: Khubvi -- Thohoyandou -- Transvaal (Limpopo) -- South Africa , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Duet performance , Xylophone , Instrumental
- Type: Music , Sound
- Identifier: vital:15947 , JKC08a-03 , http://hdl.handle.net/10962/d1009136 , Tape number: JKC08 , Original tape number: 8 , Track number: 03
- Description: Part I of duet performance of traditional Venda tune with 21 key xylophone accompaniment , For further details refer to Jaco Kruger recording card: 98
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Richard Shonisani and Ephraim Randima (Performer) , Composer unknown
- Subjects: Khubvi -- Thohoyandou -- Transvaal (Limpopo) -- South Africa , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Duet performance , Xylophone , Instrumental
- Type: Music , Sound
- Identifier: vital:15947 , JKC08a-03 , http://hdl.handle.net/10962/d1009136 , Tape number: JKC08 , Original tape number: 8 , Track number: 03
- Description: Part I of duet performance of traditional Venda tune with 21 key xylophone accompaniment , For further details refer to Jaco Kruger recording card: 98
- Full Text: false
Kwengweledzani
- Kruger, Jaco (Recorded by), Mulaudzi (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Mulaudzi (Performer) , Composer unknown
- Subjects: Hamutsha village , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Tshihwana , Bow
- Type: Music , Sound
- Identifier: vital:15532 , JKC13a-01 , http://hdl.handle.net/10962/d1008721 , Tape number: JKC13 , Original tape number: 13 , Track number: 01
- Description: English translation of title: 'Pacify' , Traditional Venda song with tshihwana musical bow accompaniment , For further details refer to Jaco Kruger recording card: 138
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Mulaudzi (Performer) , Composer unknown
- Subjects: Hamutsha village , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Tshihwana , Bow
- Type: Music , Sound
- Identifier: vital:15532 , JKC13a-01 , http://hdl.handle.net/10962/d1008721 , Tape number: JKC13 , Original tape number: 13 , Track number: 01
- Description: English translation of title: 'Pacify' , Traditional Venda song with tshihwana musical bow accompaniment , For further details refer to Jaco Kruger recording card: 138
- Full Text: false
Tshikongomuti
- Kruger, Jaco (Recorded by), Venda people (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Venda people (Performer) , Composer unknown
- Subjects: Ngudza , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Clapping , Drum , Malende dance song
- Type: Music , Sound
- Identifier: vital:15924 , JKC10a-05 , http://hdl.handle.net/10962/d1009113 , Tape number: JKC10 , Original tape number: 10 , Track number: 05
- Description: English translation of title: 'Name of a ferocious ant' , Traditional Malende Venda dance song with clapping and drum accompaniment , For further details refer to Jaco Kruger recording card: 115
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Venda people (Performer) , Composer unknown
- Subjects: Ngudza , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Clapping , Drum , Malende dance song
- Type: Music , Sound
- Identifier: vital:15924 , JKC10a-05 , http://hdl.handle.net/10962/d1009113 , Tape number: JKC10 , Original tape number: 10 , Track number: 05
- Description: English translation of title: 'Name of a ferocious ant' , Traditional Malende Venda dance song with clapping and drum accompaniment , For further details refer to Jaco Kruger recording card: 115
- Full Text: false
A comparison of the performance of selected conceptual models of the rainfall-runoff process in semi-arid catchments near Grahamstown
- Authors: Roberts, Peter J T
- Date: 1979
- Subjects: Runoff , Rainfall , South Africa , Grahamstown
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4798 , http://hdl.handle.net/10962/d1001898
- Description: A comparison of the performance of selected conceptual models of the rainfall-runoff process forms the central theme of this study and the comparison was conducted with three major objectives in mind. The first objective was to develop a conceptual model that could be used by practising hydrologists for the refinement and extension of historical streamflow records. The major requirements of the model were that it should be simple in structure and easy to operate and yet be flexible in terms of complexity of structure and input requirements as well as producing output at a level of accuracy that is competitive with that of the more complex models presently available. A comparison of the performance of the required model with that of other models formed an integral part of the development process. The second objective of the comparative study was to contribute to current knowledge of the criteria used in the selection of a suitable model for a particular application. There are, at present, no reliable guidelines to assist the hydrologist in selecting a suitable model from the wide range of models available and a comparative study would indicate the merits of various forms of model structure. The third objective is associated with the problems that arise when no streamflow data are available for model calibration. One approach is to calibrate the model in a nearby gauged catchment that the hydrologist regards as being 'hydrologically similar' and transferring the model parameter values to the ungauged catchment. Little is known about the feasibility of this parameter transfer process or about the choice of a model for such an application. The third objective was to test the feasibility of the parameter transfer process and to make use of the comparison of model performance to determine the model characteristics that are most suitable for the purpose
- Full Text:
- Date Issued: 1979
- Authors: Roberts, Peter J T
- Date: 1979
- Subjects: Runoff , Rainfall , South Africa , Grahamstown
- Language: English
- Type: Thesis , Doctoral , PhD
- Identifier: vital:4798 , http://hdl.handle.net/10962/d1001898
- Description: A comparison of the performance of selected conceptual models of the rainfall-runoff process forms the central theme of this study and the comparison was conducted with three major objectives in mind. The first objective was to develop a conceptual model that could be used by practising hydrologists for the refinement and extension of historical streamflow records. The major requirements of the model were that it should be simple in structure and easy to operate and yet be flexible in terms of complexity of structure and input requirements as well as producing output at a level of accuracy that is competitive with that of the more complex models presently available. A comparison of the performance of the required model with that of other models formed an integral part of the development process. The second objective of the comparative study was to contribute to current knowledge of the criteria used in the selection of a suitable model for a particular application. There are, at present, no reliable guidelines to assist the hydrologist in selecting a suitable model from the wide range of models available and a comparative study would indicate the merits of various forms of model structure. The third objective is associated with the problems that arise when no streamflow data are available for model calibration. One approach is to calibrate the model in a nearby gauged catchment that the hydrologist regards as being 'hydrologically similar' and transferring the model parameter values to the ungauged catchment. Little is known about the feasibility of this parameter transfer process or about the choice of a model for such an application. The third objective was to test the feasibility of the parameter transfer process and to make use of the comparison of model performance to determine the model characteristics that are most suitable for the purpose
- Full Text:
- Date Issued: 1979
The Effectiveness of Eskom’s transmission project team lationships in the delivery process
- Authors: Mpetshwa, Noninzi
- Date: 2015-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53318 , vital:45137
- Description: Eskom Holding is a public limited liability company that supplies electricity. It supplies approximately ninety-nine percent of the electricity used in South Africa, and approximately forty-five percent of that used in Africa. Eskom generates, transmits and distributes electricity to its customers. The Project Execution Department is a department in the Transmission Division that executes the capital and refurbishment of projects. The objective of the study was to discover the opinion of the project team members, on whether there is a lack of project-team efficiency in delivering the projects on time, and within the budget. Descriptive research methodology was used to investigate the objectives of the research. The data were obtained through the structured questionnaires that were hand-delivered and emailed. The research is limited to the Project Execution and Procurement Department in the Transmission Division. The research excludes the Capital Expansion Department (CED) project (Medupi, Kusile and Power Development Projects). The findings of the study showed that, Eskom’s Transmission Project Execution and Commercial Departments need to work hand-in-hand. This will avoid any unnecessary procurement delays which would have an impact on project delivery time. Continuous communication among the project team members could improve the efficiency and serve to build good relationships. Currently, projects are delivered late and over budget. This situation could lead to the outsourcing of departments or even to the redeployment of Senior Management. It would also have a negative impact on the cost and supply of electricity to the country. , Thesis (MSc) -- Faculty of Engineering, the Built Environment and Information Technology, School of the Built Environment and Civil Engineering, 2021
- Full Text:
- Date Issued: 2015-04
- Authors: Mpetshwa, Noninzi
- Date: 2015-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/53318 , vital:45137
- Description: Eskom Holding is a public limited liability company that supplies electricity. It supplies approximately ninety-nine percent of the electricity used in South Africa, and approximately forty-five percent of that used in Africa. Eskom generates, transmits and distributes electricity to its customers. The Project Execution Department is a department in the Transmission Division that executes the capital and refurbishment of projects. The objective of the study was to discover the opinion of the project team members, on whether there is a lack of project-team efficiency in delivering the projects on time, and within the budget. Descriptive research methodology was used to investigate the objectives of the research. The data were obtained through the structured questionnaires that were hand-delivered and emailed. The research is limited to the Project Execution and Procurement Department in the Transmission Division. The research excludes the Capital Expansion Department (CED) project (Medupi, Kusile and Power Development Projects). The findings of the study showed that, Eskom’s Transmission Project Execution and Commercial Departments need to work hand-in-hand. This will avoid any unnecessary procurement delays which would have an impact on project delivery time. Continuous communication among the project team members could improve the efficiency and serve to build good relationships. Currently, projects are delivered late and over budget. This situation could lead to the outsourcing of departments or even to the redeployment of Senior Management. It would also have a negative impact on the cost and supply of electricity to the country. , Thesis (MSc) -- Faculty of Engineering, the Built Environment and Information Technology, School of the Built Environment and Civil Engineering, 2021
- Full Text:
- Date Issued: 2015-04
Ku lila Parts II and III
- Kruger, Jaco (Recorded by), Lambani family (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Lambani family (Performer) , Composer unknown
- Subjects: Halambani , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Xylophone , Mbila
- Type: Music , Sound
- Identifier: vital:16116 , JKC14a-15 , http://hdl.handle.net/10962/d1009305 , Tape number: JKC14 , Original tape number: 14 , Track number: 15
- Description: English translation of title: 'The ground hornbills are crying' , Parts II and III of traditional Venda song accompanied by the 21 key xylophone , For further details refer to Jaco Kruger recording card: 147
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Lambani family (Performer) , Composer unknown
- Subjects: Halambani , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Xylophone , Mbila
- Type: Music , Sound
- Identifier: vital:16116 , JKC14a-15 , http://hdl.handle.net/10962/d1009305 , Tape number: JKC14 , Original tape number: 14 , Track number: 15
- Description: English translation of title: 'The ground hornbills are crying' , Parts II and III of traditional Venda song accompanied by the 21 key xylophone , For further details refer to Jaco Kruger recording card: 147
- Full Text: false
Factors influencing rentention of academic staff at South African higher education institutions
- Authors: Maphiri, Thabiso
- Date: 2020-04
- Subjects: Grahamstown (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54739 , vital:47653
- Description: The study investigated the factors influencing retention of academic staff at South African Higher Education Institutions (HEIs). The Job Embeddedness theory and Herzberg’s theory on retention were used to explore the retention of employees with special focus on the challenges and strategies of enhancing retention. The study adopted desktop research to explore the retention of academic staff in HEIs. This study discussed the challenges and factors influencing staff retention in universities and Technical and Vocational Education and Training colleges (TVETs) in South Africa. The findings of the study revealed that the challenges that impede staff retention include a lack of capacity; massification of tertiary education; transformation of higher education; redressing historical imbalances; staff turnover; a lack of mentoring and coaching; and the impossibility to satisfy everyone’s needs. The study identified strategies that can be adopted to enhance staff retention that focus on remuneration and compensation; professional development; workplace climate; appointments and promotions; institutional governance; institutional infrastructure and adaptation to change. Factors that contribute to effective staff retention were also identified as organisational culture; the rewards system; mentoring and development programmes; retention tracking, recruitment; selection; the life cycle of an employee; onboarding; performance management systems, career management, bureaucratic organisational structures; and effective support from Deans and Vice-Chancellors. Lastly, the study recommended the following on how HEIs can retain their academic staff: career advancement opportunities to boost morale and loyalty of the staff; mentoring and coaching provided to the junior staff by the senior staff; job satisfaction through the provision of remuneration and rewarding performance; and implementing sound performance management and appraisal systems. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2020
- Full Text:
- Date Issued: 2020-04
- Authors: Maphiri, Thabiso
- Date: 2020-04
- Subjects: Grahamstown (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54739 , vital:47653
- Description: The study investigated the factors influencing retention of academic staff at South African Higher Education Institutions (HEIs). The Job Embeddedness theory and Herzberg’s theory on retention were used to explore the retention of employees with special focus on the challenges and strategies of enhancing retention. The study adopted desktop research to explore the retention of academic staff in HEIs. This study discussed the challenges and factors influencing staff retention in universities and Technical and Vocational Education and Training colleges (TVETs) in South Africa. The findings of the study revealed that the challenges that impede staff retention include a lack of capacity; massification of tertiary education; transformation of higher education; redressing historical imbalances; staff turnover; a lack of mentoring and coaching; and the impossibility to satisfy everyone’s needs. The study identified strategies that can be adopted to enhance staff retention that focus on remuneration and compensation; professional development; workplace climate; appointments and promotions; institutional governance; institutional infrastructure and adaptation to change. Factors that contribute to effective staff retention were also identified as organisational culture; the rewards system; mentoring and development programmes; retention tracking, recruitment; selection; the life cycle of an employee; onboarding; performance management systems, career management, bureaucratic organisational structures; and effective support from Deans and Vice-Chancellors. Lastly, the study recommended the following on how HEIs can retain their academic staff: career advancement opportunities to boost morale and loyalty of the staff; mentoring and coaching provided to the junior staff by the senior staff; job satisfaction through the provision of remuneration and rewarding performance; and implementing sound performance management and appraisal systems. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2020
- Full Text:
- Date Issued: 2020-04
Encapsulation of flame retardants for lithium-ion battery safety
- Authors: Ntombela, Nompilo Princess
- Date: 2022-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55412 , vital:51993
- Description: Lithium-ion technology takes the lead in electric mobility systems, resulting in an increase in the global demand for Li-ion batteries; however, these batteries are associated with numerous safety concerns. Additionally, there are high costs, high energy and power issues which are some of its key limitations. Research efforts are focused on overcoming these obstacles, with different approaches being explored, such as the investigation of more stable salts, modification of active materials and organic solvents, and the use of electrolyte additives. This study focused specifically on electrolyte additives since the electrolyte is one of the most unstable components of the battery. The electrolyte’s decomposition is one of the reactions that occur inside a battery, which may occur due to overcharging or due to an internal short circuit, amongst others. The electrolyte’s decomposition occurs at the early stages of the thermal runaway process and forms part of the reactions that lead to fires and explosions. Thus, this research aims to develop suitable electrolyte additives to improve the safety aspects of Li-ion batteries. Flame retardant additives show great promise in reducing the flammability of the electrolyte in Li-ion batteries, since they serve to suppress the chemical reactions associated with battery ignition. They retard the fires by scavenging the active radical species formed during the decomposition reaction. In this study, the use of flame retardants was investigated. Flame retardant additives have shown to have flame impeding properties inside a battery; however, their direct addition to the electrolyte tends to cause adverse effects on the ionic conductivity and electrochemical performance of the cells. This study investigated an alternative option - the option to microencapsulate such additives into a neutral compound to ensure that the flame retardant has minimal/no effect on the performance of the battery. This investigation looked at tris(2-butoxyethyl) phosphate (TBP) and bis(2,2,2-trifluoroethyl) methylphosphonate (BFP) as flame retardant additives for the electrolyte. The TBP and BFP flame retardants were microencapsulated in poly(urea formaldehyde) (PUF) coating material via in situ polymerization method. The capsules were characterized using various analytical techniques - to prove it was successfully encapsulated. Electrochemical studies were further done on the capsules and neat flame retardants inside a coin cell. Self-extinguishing time (SET), which is the flammability test, proved that the additives have flame retarding abilities. Opto-digital microscopy (DSX) and scanning electron microscopy (SEM) did confirm the spherical shape of the microcapsules, where SEM also showed the smooth outer layer of the microcapsules and its hollow inner side. Fourier transform infrared spectroscopy (FTIR) proved the presence of the TBP and BFP inside the PUF resin by showing that the chemical composition of microcapsules consisted of both the PUF and flame retardant additives. Simultaneous DSC-TGA (DST) was also performed which showed that the microcapsules were stable before 200 °C, which indicates it would not decompose before the thermal runaway events are occurring. TGA analysis did show that the microcapsules underwent multiple decomposition steps upon heating. Additionally, 31P nuclear magnetic resonance (NMR) was used to quantify the amount of flame retardants additives encapsulated inside PUF shell, and also confirmed the stability of the microcapsules for one month in the electrolyte and at temperatures up to 200 °C. The ionic conductivity was vastly decreased when the flame retardants were added directly to the electrolyte. However, adding the flame retardants in a form of capsules had minimal effect on the ionic conductivity. The cycle capacities of the capsules were also improved when the capsules were added to the cell compared to that of neat flame retardants. The same effect was also noticed when doing Electrochemical Impedance Spectroscopy (EIS). This shows that microencapsulation improves the resistance of the cell caused by the flame retardant in comparison to when added directly to the electrolyte of the cell. , Thesis (MSC) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2022
- Full Text:
- Date Issued: 2022-04
- Authors: Ntombela, Nompilo Princess
- Date: 2022-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/55412 , vital:51993
- Description: Lithium-ion technology takes the lead in electric mobility systems, resulting in an increase in the global demand for Li-ion batteries; however, these batteries are associated with numerous safety concerns. Additionally, there are high costs, high energy and power issues which are some of its key limitations. Research efforts are focused on overcoming these obstacles, with different approaches being explored, such as the investigation of more stable salts, modification of active materials and organic solvents, and the use of electrolyte additives. This study focused specifically on electrolyte additives since the electrolyte is one of the most unstable components of the battery. The electrolyte’s decomposition is one of the reactions that occur inside a battery, which may occur due to overcharging or due to an internal short circuit, amongst others. The electrolyte’s decomposition occurs at the early stages of the thermal runaway process and forms part of the reactions that lead to fires and explosions. Thus, this research aims to develop suitable electrolyte additives to improve the safety aspects of Li-ion batteries. Flame retardant additives show great promise in reducing the flammability of the electrolyte in Li-ion batteries, since they serve to suppress the chemical reactions associated with battery ignition. They retard the fires by scavenging the active radical species formed during the decomposition reaction. In this study, the use of flame retardants was investigated. Flame retardant additives have shown to have flame impeding properties inside a battery; however, their direct addition to the electrolyte tends to cause adverse effects on the ionic conductivity and electrochemical performance of the cells. This study investigated an alternative option - the option to microencapsulate such additives into a neutral compound to ensure that the flame retardant has minimal/no effect on the performance of the battery. This investigation looked at tris(2-butoxyethyl) phosphate (TBP) and bis(2,2,2-trifluoroethyl) methylphosphonate (BFP) as flame retardant additives for the electrolyte. The TBP and BFP flame retardants were microencapsulated in poly(urea formaldehyde) (PUF) coating material via in situ polymerization method. The capsules were characterized using various analytical techniques - to prove it was successfully encapsulated. Electrochemical studies were further done on the capsules and neat flame retardants inside a coin cell. Self-extinguishing time (SET), which is the flammability test, proved that the additives have flame retarding abilities. Opto-digital microscopy (DSX) and scanning electron microscopy (SEM) did confirm the spherical shape of the microcapsules, where SEM also showed the smooth outer layer of the microcapsules and its hollow inner side. Fourier transform infrared spectroscopy (FTIR) proved the presence of the TBP and BFP inside the PUF resin by showing that the chemical composition of microcapsules consisted of both the PUF and flame retardant additives. Simultaneous DSC-TGA (DST) was also performed which showed that the microcapsules were stable before 200 °C, which indicates it would not decompose before the thermal runaway events are occurring. TGA analysis did show that the microcapsules underwent multiple decomposition steps upon heating. Additionally, 31P nuclear magnetic resonance (NMR) was used to quantify the amount of flame retardants additives encapsulated inside PUF shell, and also confirmed the stability of the microcapsules for one month in the electrolyte and at temperatures up to 200 °C. The ionic conductivity was vastly decreased when the flame retardants were added directly to the electrolyte. However, adding the flame retardants in a form of capsules had minimal effect on the ionic conductivity. The cycle capacities of the capsules were also improved when the capsules were added to the cell compared to that of neat flame retardants. The same effect was also noticed when doing Electrochemical Impedance Spectroscopy (EIS). This shows that microencapsulation improves the resistance of the cell caused by the flame retardant in comparison to when added directly to the electrolyte of the cell. , Thesis (MSC) -- Faculty of Science, School of Biomolecular and Chemical Sciences, 2022
- Full Text:
- Date Issued: 2022-04
Luimbo Part I
- Kruger, Jaco (Recorded by), Mudanalwo Takalani and Kruger (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Mudanalwo Takalani and Kruger (Performer) , Composer unknown
- Subjects: Ngwenani , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Instrumental , Xylophone , Mbila , Duet performance
- Type: Music , Sound
- Identifier: vital:15548 , JKC14b-02 , http://hdl.handle.net/10962/d1008737 , Tape number: JKC14 , Original tape number: 14 , Track number: 02
- Description: Part I of duet performance of traditional Venda tune with 21 key xylophone accompaniment , For further details refer to Jaco Kruger recording card: 150
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Mudanalwo Takalani and Kruger (Performer) , Composer unknown
- Subjects: Ngwenani , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Instrumental , Xylophone , Mbila , Duet performance
- Type: Music , Sound
- Identifier: vital:15548 , JKC14b-02 , http://hdl.handle.net/10962/d1008737 , Tape number: JKC14 , Original tape number: 14 , Track number: 02
- Description: Part I of duet performance of traditional Venda tune with 21 key xylophone accompaniment , For further details refer to Jaco Kruger recording card: 150
- Full Text: false
Sketch map of the portion of the territory of East Griqualand : traversed while settling locations by the vacant Land Commissioners
- Brownlee, C, Strachan, Donald, Watermeyer, C P, Watermeyer, F S, Cape of Good Hope (Colony). Surveyor General, Surveyor General's Department, Saul Solomon & Co.
- Authors: Brownlee, C , Strachan, Donald , Watermeyer, C P , Watermeyer, F S , Cape of Good Hope (Colony). Surveyor General , Surveyor General's Department , Saul Solomon & Co.
- Date: 1883
- Subjects: East Griqualand (South Africa) -- Administrative and political divisions -- Maps Maps , South Africa
- Language: English
- Type: map , cartographic
- Identifier: http://hdl.handle.net/10962/62099 , vital:28127 , Cory Library for Humanities Research, Rhodes University Library, Grahamstown, South Africa
- Description: Sketch map of the portion of the territory of East Griqualand : traversed while settling locations by the vacant Land Commissioners. The Hon. C. Brownlee, CMG Donald Strachan and CP Watermeyer in June-September 1883.
- Full Text: false
- Date Issued: 1883
- Authors: Brownlee, C , Strachan, Donald , Watermeyer, C P , Watermeyer, F S , Cape of Good Hope (Colony). Surveyor General , Surveyor General's Department , Saul Solomon & Co.
- Date: 1883
- Subjects: East Griqualand (South Africa) -- Administrative and political divisions -- Maps Maps , South Africa
- Language: English
- Type: map , cartographic
- Identifier: http://hdl.handle.net/10962/62099 , vital:28127 , Cory Library for Humanities Research, Rhodes University Library, Grahamstown, South Africa
- Description: Sketch map of the portion of the territory of East Griqualand : traversed while settling locations by the vacant Land Commissioners. The Hon. C. Brownlee, CMG Donald Strachan and CP Watermeyer in June-September 1883.
- Full Text: false
- Date Issued: 1883
Sketch of ground in Keiskamma Hoek, Jan 22, 1852
- Date: 1852
- Subjects: Keiskammahoek (South Africa) -- Maps Maps , Cape of Good Hope (Colony) -- Maps Maps , South Africa
- Language: English
- Type: cartographic , map
- Identifier: http://hdl.handle.net/10962/57451 , vital:26927 , Cory Library for Humanities Research, Rhodes University Library, Grahamstown, South Africa MP54 , MP54
- Full Text: false
- Date Issued: 1852
- Date: 1852
- Subjects: Keiskammahoek (South Africa) -- Maps Maps , Cape of Good Hope (Colony) -- Maps Maps , South Africa
- Language: English
- Type: cartographic , map
- Identifier: http://hdl.handle.net/10962/57451 , vital:26927 , Cory Library for Humanities Research, Rhodes University Library, Grahamstown, South Africa MP54 , MP54
- Full Text: false
- Date Issued: 1852
Mbula dzanga Part II
- Kruger, Jaco (Recorded by), Mudanalwo Takalani and Kruger (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Mudanalwo Takalani and Kruger (Performer) , Composer unknown
- Subjects: Ngwenani , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Xylophone , Mbila , Duet performance
- Type: Music , Sound
- Identifier: vital:15602 , JKC14b-03 , http://hdl.handle.net/10962/d1008791 , Tape number: JKC14 , Original tape number: 14 , Track number: 03
- Description: Part II of duet performance of traditional Venda song accompanied by the 21 key xylophone , For further details refer to Jaco Kruger recording card: 150
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Mudanalwo Takalani and Kruger (Performer) , Composer unknown
- Subjects: Ngwenani , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Xylophone , Mbila , Duet performance
- Type: Music , Sound
- Identifier: vital:15602 , JKC14b-03 , http://hdl.handle.net/10962/d1008791 , Tape number: JKC14 , Original tape number: 14 , Track number: 03
- Description: Part II of duet performance of traditional Venda song accompanied by the 21 key xylophone , For further details refer to Jaco Kruger recording card: 150
- Full Text: false
An anthropological enquiry on the perceptions of adults on female sterilisation: a case of Gunguluza township
- Authors: Mbanjwa, Mpho
- Date: 2021-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54859 , vital:48085
- Description: The purpose of the study was to make an enquiry on the perceptions on female sterilisation adult participants, residing in Gunguluza Township, Uitenhage had. A qualitative research approach was used to collect the responses of 10 participants. These included eight women, one man and one traditional healer registered within the Traditional Healers Association of South Africa. The interviews had been semistructured with open-ended questions pre-set to help the researcher guide the conversation. Conversation analysis was the technique used to transform the information into research data that would attempt to answer the research question. The question this research attempted to answer was to form an understanding of how information and education resources provided by both Western and Traditional sources, including their availability and accessibility with regards to female sterilisation, as a form of contraception, have been understood, received and interpreted by adults residing in the research area of Gunguluza township. Gunguluza forms part of the area formally known as the Kwanobuhle 10 and Kwanobuhle 11 respectively. Some limitations, including limiting resources that resulted in only 10 participants being interviewed. The results had shown that participants had shown interest in acquiring more knowledge about female sterilisation and other reproductive health issues, in order to make informed decisions about their bodies, with contraceptive choice and use in particular. Most felt the need to engage with their partners about the choice of sterilisation largely due to the support they would need. With regard to traditional health as an alternative or interchangeable method of contraception, participants had very little knowledge of, with some expressing some importance and relevance in acquiring such knowledge, in a modern context. These findings came with sets of recommendations which placed an emphasis on the building of indigenous knowledge and its inclusion in formal spaces for open engagement and discussion. Traditional knowledge needed to be transferred from an oral to being documented into literature for future preservation and to eliminate any distortion. There was a gap for formal western medicine to collaborate or accommodate traditional medicine. The study made use of female sterilisation as a conceptual framework, with time and more future research could build and produce new theoretical understandings of the concept, from an Afrocentric context in particular. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-04
- Authors: Mbanjwa, Mpho
- Date: 2021-04
- Subjects: Port Elizabeth (South Africa) , Eastern Cape (South Africa) , South Africa
- Language: English
- Type: Master's theses , text
- Identifier: http://hdl.handle.net/10948/54859 , vital:48085
- Description: The purpose of the study was to make an enquiry on the perceptions on female sterilisation adult participants, residing in Gunguluza Township, Uitenhage had. A qualitative research approach was used to collect the responses of 10 participants. These included eight women, one man and one traditional healer registered within the Traditional Healers Association of South Africa. The interviews had been semistructured with open-ended questions pre-set to help the researcher guide the conversation. Conversation analysis was the technique used to transform the information into research data that would attempt to answer the research question. The question this research attempted to answer was to form an understanding of how information and education resources provided by both Western and Traditional sources, including their availability and accessibility with regards to female sterilisation, as a form of contraception, have been understood, received and interpreted by adults residing in the research area of Gunguluza township. Gunguluza forms part of the area formally known as the Kwanobuhle 10 and Kwanobuhle 11 respectively. Some limitations, including limiting resources that resulted in only 10 participants being interviewed. The results had shown that participants had shown interest in acquiring more knowledge about female sterilisation and other reproductive health issues, in order to make informed decisions about their bodies, with contraceptive choice and use in particular. Most felt the need to engage with their partners about the choice of sterilisation largely due to the support they would need. With regard to traditional health as an alternative or interchangeable method of contraception, participants had very little knowledge of, with some expressing some importance and relevance in acquiring such knowledge, in a modern context. These findings came with sets of recommendations which placed an emphasis on the building of indigenous knowledge and its inclusion in formal spaces for open engagement and discussion. Traditional knowledge needed to be transferred from an oral to being documented into literature for future preservation and to eliminate any distortion. There was a gap for formal western medicine to collaborate or accommodate traditional medicine. The study made use of female sterilisation as a conceptual framework, with time and more future research could build and produce new theoretical understandings of the concept, from an Afrocentric context in particular. , Thesis (MA) -- Faculty of Humanities, School of Governmental and Social Sciences, 2021
- Full Text:
- Date Issued: 2021-04
Matamba ni ya dovhana
- Kruger, Jaco (Recorded by), Mphaphuli, John (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Mphaphuli, John (Performer) , Composer unknown
- Subjects: Khubvi -- Thohoyandou -- Transvaal (Limpopo) -- South Africa , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Lamellophone , Mbira , Solo
- Type: Music , Sound
- Identifier: vital:15581 , JKC03b-12 , http://hdl.handle.net/10962/d1008770 , Tape number: JKC03 , Original tape number: 3 , Track number: 12
- Description: Traditional Venda song with mbira accompaniment , For further details refer to Jaco Kruger recording card: 62
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Mphaphuli, John (Performer) , Composer unknown
- Subjects: Khubvi -- Thohoyandou -- Transvaal (Limpopo) -- South Africa , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional song , Lamellophone , Mbira , Solo
- Type: Music , Sound
- Identifier: vital:15581 , JKC03b-12 , http://hdl.handle.net/10962/d1008770 , Tape number: JKC03 , Original tape number: 3 , Track number: 12
- Description: Traditional Venda song with mbira accompaniment , For further details refer to Jaco Kruger recording card: 62
- Full Text: false
Tshidudu tsha makhulu Matodzi
- Kruger, Jaco (Recorded by), Munyai, James (Performer), Munyai, James (Composer)
- Authors: Kruger, Jaco (Recorded by) , Munyai, James (Performer) , Munyai, James (Composer)
- Subjects: Tshaulu , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Mbila dza madeze , Vocal
- Type: Music , Sound
- Identifier: vital:15893 , JKC02b-04 , http://hdl.handle.net/10962/d1009082 , Tape number: JKC02 , Original tape number: 2 , Track number: 04
- Description: English translation of title: 'A small clay-pot of grandmother Matodzi' , Traditional Venda song accompanied by the mbila dza madeze , For further details refer to Jaco Kruger recording card: 44
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Munyai, James (Performer) , Munyai, James (Composer)
- Subjects: Tshaulu , Thohoyandou -- Transvaal (Limpopo) -- South Africa , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Mbila dza madeze , Vocal
- Type: Music , Sound
- Identifier: vital:15893 , JKC02b-04 , http://hdl.handle.net/10962/d1009082 , Tape number: JKC02 , Original tape number: 2 , Track number: 04
- Description: English translation of title: 'A small clay-pot of grandmother Matodzi' , Traditional Venda song accompanied by the mbila dza madeze , For further details refer to Jaco Kruger recording card: 44
- Full Text: false
Vha na madambi vha toda u lila
- Kruger, Jaco (Recorded by), Mukuni, Tshinakao (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Mukuni, Tshinakao (Performer) , Composer unknown
- Subjects: Malavuhe , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Bow , Tshihwana , Solo
- Type: Music , Sound
- Identifier: vital:16002 , JKC04b-10 , http://hdl.handle.net/10962/d1009191 , Tape number: JKC04 , Original tape number: 4 , Track number: 10
- Description: English translation of title: 'A reference to crying caused by magic' , Traditional Venda song with tshihwana bow accompaniment , For further details refer to Jaco Kruger recording card: 70
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Mukuni, Tshinakao (Performer) , Composer unknown
- Subjects: Malavuhe , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Bow , Tshihwana , Solo
- Type: Music , Sound
- Identifier: vital:16002 , JKC04b-10 , http://hdl.handle.net/10962/d1009191 , Tape number: JKC04 , Original tape number: 4 , Track number: 10
- Description: English translation of title: 'A reference to crying caused by magic' , Traditional Venda song with tshihwana bow accompaniment , For further details refer to Jaco Kruger recording card: 70
- Full Text: false
Nzekenzekenzeke
- Kruger, Jaco (Recorded by), Musisinyani, Piet (Performer), Composer unknown
- Authors: Kruger, Jaco (Recorded by) , Musisinyani, Piet (Performer) , Composer unknown
- Subjects: Mangaya , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Bow , Mbila , Children's dance song
- Type: Music , Sound
- Identifier: vital:15695 , JKC09b-11 , http://hdl.handle.net/10962/d1008884 , Tape number: JKC09 , Original tape number: 9 , Track number: 11
- Description: Traditional Venda children's dance song accompanied by the tshizambi friction musical bow , For further details refer to Jaco Kruger recording card: 112
- Full Text: false
- Authors: Kruger, Jaco (Recorded by) , Musisinyani, Piet (Performer) , Composer unknown
- Subjects: Mangaya , Transvaal (Limpopo) , South Africa , Indigenous music , Traditional music , Bow , Mbila , Children's dance song
- Type: Music , Sound
- Identifier: vital:15695 , JKC09b-11 , http://hdl.handle.net/10962/d1008884 , Tape number: JKC09 , Original tape number: 9 , Track number: 11
- Description: Traditional Venda children's dance song accompanied by the tshizambi friction musical bow , For further details refer to Jaco Kruger recording card: 112
- Full Text: false