Iron perchlorophthalocyanine and tetrasulfophthalocyanine catalyzed oxidation of cyclohexane using hydrogen peroxide, chloroperoxybenzoic acid and tert-butylhydroperoxide as oxidants
- Grootboom, Natasha, Nyokong, Tebello
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289606 , vital:56653 , xlink:href="https://doi.org/10.1016/S1381-1169(01)00404-6"
- Description: Polychlorophthalocyanine (Cl16PcFeII) and tetrasulfophthalocyanine ([FeIITSPc]4−) complexes of iron are employed as catalysts for the oxidation of cyclohexane using tert-butyl hydroperoxide (TBHP), m-chloroperoxybenzoic acid (m-CPBA) and hydrogen peroxide as oxidants. Catalysis using the Cl16PcFeII was performed in a dimethylformamide:dichloromethane (3:7) solvent mixture. For the [FeIITSPc]4−catalyst, a water:methanol (1:9) mixture was employed. The products of the catalysis are cyclohexanone, cyclohexanol and cyclohexanediol. The relative yields of the products depended on oxidant and the catalyst. TBHP was found to be the best oxidant since minimal destruction of the catalyst and higher selectivity in the products were observed when this oxidant was employed. The mechanism of the oxidation of cyclohexane in the presence of the Cl16PcFeII and [FeIITSPc]4− involves the oxidation of these catalysts, forming an Fe(III) phthalocyanine species as an intermediate. Higher yields were observed when [FeTSPc]4− was employed as a catalyst, which is more soluble than the perchlorinated iron phthalocyanine catalyst.
- Full Text:
- Date Issued: 2002
- Authors: Grootboom, Natasha , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289606 , vital:56653 , xlink:href="https://doi.org/10.1016/S1381-1169(01)00404-6"
- Description: Polychlorophthalocyanine (Cl16PcFeII) and tetrasulfophthalocyanine ([FeIITSPc]4−) complexes of iron are employed as catalysts for the oxidation of cyclohexane using tert-butyl hydroperoxide (TBHP), m-chloroperoxybenzoic acid (m-CPBA) and hydrogen peroxide as oxidants. Catalysis using the Cl16PcFeII was performed in a dimethylformamide:dichloromethane (3:7) solvent mixture. For the [FeIITSPc]4−catalyst, a water:methanol (1:9) mixture was employed. The products of the catalysis are cyclohexanone, cyclohexanol and cyclohexanediol. The relative yields of the products depended on oxidant and the catalyst. TBHP was found to be the best oxidant since minimal destruction of the catalyst and higher selectivity in the products were observed when this oxidant was employed. The mechanism of the oxidation of cyclohexane in the presence of the Cl16PcFeII and [FeIITSPc]4− involves the oxidation of these catalysts, forming an Fe(III) phthalocyanine species as an intermediate. Higher yields were observed when [FeTSPc]4− was employed as a catalyst, which is more soluble than the perchlorinated iron phthalocyanine catalyst.
- Full Text:
- Date Issued: 2002
Fuel wood use in South Africa: Where to in the 21st Century?
- Williams, Anthony, Shackleton, Charlie M
- Authors: Williams, Anthony , Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183026 , vital:43905 , xlink:href="https://doi.org/10.1080/20702620.2002.10434611"
- Description: South Africa is well known for the dichotomous nature of its economy, with its juxtaposed first and third world characteristics, perhaps nowhere more starkly evident than in the energy sector. South Africa produces and consumes over 60% of the total electrical energy on the African continent, and is ranked twelfth in the world in terms of carbon emissions (EIA, 2002). Yet the majority of the South African population does not have access to electricity, and despite the enormous strides taken since 1994 to increase household access to electricity (NER, 2001), newly electrified households, more often than not, cannot afford the appliances nor the monthly costs required to significantly improve their quality of life (White et al., 1997). Thus, most rural and many peri-urban households continue to use fuelwood as their primary energy source (Griffin et al., 1992; Dyer, 1996; Kotze, 1996; Williams et al., 1996). Fuelwood use presents both opportunities and risks.
- Full Text:
- Date Issued: 2002
- Authors: Williams, Anthony , Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/183026 , vital:43905 , xlink:href="https://doi.org/10.1080/20702620.2002.10434611"
- Description: South Africa is well known for the dichotomous nature of its economy, with its juxtaposed first and third world characteristics, perhaps nowhere more starkly evident than in the energy sector. South Africa produces and consumes over 60% of the total electrical energy on the African continent, and is ranked twelfth in the world in terms of carbon emissions (EIA, 2002). Yet the majority of the South African population does not have access to electricity, and despite the enormous strides taken since 1994 to increase household access to electricity (NER, 2001), newly electrified households, more often than not, cannot afford the appliances nor the monthly costs required to significantly improve their quality of life (White et al., 1997). Thus, most rural and many peri-urban households continue to use fuelwood as their primary energy source (Griffin et al., 1992; Dyer, 1996; Kotze, 1996; Williams et al., 1996). Fuelwood use presents both opportunities and risks.
- Full Text:
- Date Issued: 2002
Asthenospheric and lithospheric sources for Mesozoic dolerites from Liberia (Africa): trace element and isotopic evidence
- Dupuy, C, Marsh, J, Dostal, J, Michard, A, Testa, S
- Authors: Dupuy, C , Marsh, J , Dostal, J , Michard, A , Testa, S
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/140422 , vital:37887 , https://doi.org/10.1016/0012-821X(88)90067-2
- Description: Combined elemental, and Sr and Nd isotopic data are presented for Mesozoic dolerite dikes of Liberia (Africa) which are related to the initial stage of opening of the Atlantic Ocean.
- Full Text: false
- Date Issued: 2002
- Authors: Dupuy, C , Marsh, J , Dostal, J , Michard, A , Testa, S
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/140422 , vital:37887 , https://doi.org/10.1016/0012-821X(88)90067-2
- Description: Combined elemental, and Sr and Nd isotopic data are presented for Mesozoic dolerite dikes of Liberia (Africa) which are related to the initial stage of opening of the Atlantic Ocean.
- Full Text: false
- Date Issued: 2002
pH study of the electrocatalytic SO2 detection at a glassy carbon electrode modified with iron (II) tetrasulfophthalocyanine
- Thamae, Mamothibe, Westbroek, Philippe, Nyokong, Tebello
- Authors: Thamae, Mamothibe , Westbroek, Philippe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304786 , vital:58490 , xlink:href="https://doi.org/10.1007/s00604-002-0914-8"
- Description: The electrocatalytic determination of SO2 is studied as a function of pH at a glassy carbon electrode modified with iron(II)tetrasulfophthalocyanine ([Fe(II)TSPc]4−). It was found in the literature that depending on pH, SO2·xH2O, HSO3 − and/or SO3 2− are the main compounds in solution, that these compounds behave differently at the electrode surface, and that the condition of the electrode surface is stable over the entire pH-range. The use of SO2(g) or sodium sulfite as starting material did result in identical curves except in the pH range from 7.5–9.0. A possible explanation could be given by proposing that SO2·xH2O is very unstable in the presence of SO3 2−. In strongly acidic medium, SO2·xH2O is the main compound, which can be oxidized as well as reduced with exchange of two electrons. HSO3 − is the main compound at pH = 4 and can also be oxidized and reduced with exchange of, respectively, two and four electrons. In alkaline solution sulfite is the main compound and can only be oxidized, also under exchange of two electrons. Detection limits are in the range of 4.0 ± 0.1 × 10−5 and 7.5 ± 0.1 × 10−5 mol L−1, dependent of pH and of the type of reaction (oxidation or reduction) used.
- Full Text:
- Date Issued: 2002
- Authors: Thamae, Mamothibe , Westbroek, Philippe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/304786 , vital:58490 , xlink:href="https://doi.org/10.1007/s00604-002-0914-8"
- Description: The electrocatalytic determination of SO2 is studied as a function of pH at a glassy carbon electrode modified with iron(II)tetrasulfophthalocyanine ([Fe(II)TSPc]4−). It was found in the literature that depending on pH, SO2·xH2O, HSO3 − and/or SO3 2− are the main compounds in solution, that these compounds behave differently at the electrode surface, and that the condition of the electrode surface is stable over the entire pH-range. The use of SO2(g) or sodium sulfite as starting material did result in identical curves except in the pH range from 7.5–9.0. A possible explanation could be given by proposing that SO2·xH2O is very unstable in the presence of SO3 2−. In strongly acidic medium, SO2·xH2O is the main compound, which can be oxidized as well as reduced with exchange of two electrons. HSO3 − is the main compound at pH = 4 and can also be oxidized and reduced with exchange of, respectively, two and four electrons. In alkaline solution sulfite is the main compound and can only be oxidized, also under exchange of two electrons. Detection limits are in the range of 4.0 ± 0.1 × 10−5 and 7.5 ± 0.1 × 10−5 mol L−1, dependent of pH and of the type of reaction (oxidation or reduction) used.
- Full Text:
- Date Issued: 2002
Effects of axial ligands on the photophysical properties of silicon octaphenoxyphthalocyanine
- Maree, M David, Nyokong, Tebello, Suhling, Klaus, Phillips, David
- Authors: Maree, M David , Nyokong, Tebello , Suhling, Klaus , Phillips, David
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289582 , vital:56651 , xlink:href="https://doi.org/10.1142/S1088424602000452"
- Description: The photochemistry and photophysics of six axially substituted silicon phthalocyanines are reported and show the importance of the axial groups in the photochemistry of these compounds. The fluorescence quantum yields are especially affected by the axial ligand. A very good correlation was found for the experimentally determined fluorescence lifetimes and the theoretically determined lifetimes using the Strickler-Berg equation for the unaggregated molecules.
- Full Text:
- Date Issued: 2002
- Authors: Maree, M David , Nyokong, Tebello , Suhling, Klaus , Phillips, David
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289582 , vital:56651 , xlink:href="https://doi.org/10.1142/S1088424602000452"
- Description: The photochemistry and photophysics of six axially substituted silicon phthalocyanines are reported and show the importance of the axial groups in the photochemistry of these compounds. The fluorescence quantum yields are especially affected by the axial ligand. A very good correlation was found for the experimentally determined fluorescence lifetimes and the theoretically determined lifetimes using the Strickler-Berg equation for the unaggregated molecules.
- Full Text:
- Date Issued: 2002
An assessment of the efficacy of two lysine microencapsulation techniques to determine the quantitative lysine requirement of the South African abalone, Haliotis midae L
- Shipton, Thomas A, Britz, Peter J, Walker, Roderick B
- Authors: Shipton, Thomas A , Britz, Peter J , Walker, Roderick B
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184289 , vital:44197 , xlink:href="https://doi.org/10.1046/j.1365-2095.2002.00204.x"
- Description: The quantification of the essential amino acid requirements of a species is a prerequisite to the formulation of biologically optimized diets. In this study, crystalline L-lysine was used in an attempt to determine the quantitative lysine requirement of juvenile Haliotis midae. Two microencapsulation techniques [gelatine/acacia and cellulose acetate phthalate (CAP)] were used to retard leaching of crystalline L-lysine incorporated into semipurified test diets. An assessment of the efficacy of the encapsulation techniques, revealed that despite effective lysine supplementation, H. midae fed semipurified test diets containing encapsulated crystalline L-lysine failed to promote significant improvements in either growth, feed or protein efficiency (P > 0.05). The failure of the crystalline L-lysine to illicit growth and nutritional responses is discussed.
- Full Text:
- Date Issued: 2002
- Authors: Shipton, Thomas A , Britz, Peter J , Walker, Roderick B
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184289 , vital:44197 , xlink:href="https://doi.org/10.1046/j.1365-2095.2002.00204.x"
- Description: The quantification of the essential amino acid requirements of a species is a prerequisite to the formulation of biologically optimized diets. In this study, crystalline L-lysine was used in an attempt to determine the quantitative lysine requirement of juvenile Haliotis midae. Two microencapsulation techniques [gelatine/acacia and cellulose acetate phthalate (CAP)] were used to retard leaching of crystalline L-lysine incorporated into semipurified test diets. An assessment of the efficacy of the encapsulation techniques, revealed that despite effective lysine supplementation, H. midae fed semipurified test diets containing encapsulated crystalline L-lysine failed to promote significant improvements in either growth, feed or protein efficiency (P > 0.05). The failure of the crystalline L-lysine to illicit growth and nutritional responses is discussed.
- Full Text:
- Date Issued: 2002
Voltammetric detection of vitamin B1 at carbon paste electrodes and its determination in tablets
- Oni, Joshua, Westbroek, Philippe, Nyokong, Tebello
- Authors: Oni, Joshua , Westbroek, Philippe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289692 , vital:56663 , xlink:href="https://doi.org/10.1002/1521-4109(200209)14"
- Description: The voltammetric behavior of vitamin B1 in alkaline medium at carbon paste electrode (CPE) is discussed. A method based on cyclic voltammetry for the determination of vitamin B1 at carbon paste electrode modified with manganese phthalocyanine (MnPc-CPE) is presented. In pH 10 buffer, the modified electrode showed catalytic activity towards the oxidation of vitamin B1 by considerably increasing the oxidation current of one of the observed waves compared to the oxidation current obtained at an unmodified electrode. The modified electrode was stable towards the determination of vitamin B1 compared to the unmodified electrode that is completely poisoned after a few scans. A linear relationship between the oxidation current and the concentration of vitamin B1 in solution was observed. The detection limit for vitamin B1 at the modified electrode was of the order of 10−5 mol dm−3. Commercial vitamin B1 tablets were analyzed using the modified electrodes.
- Full Text:
- Date Issued: 2002
- Authors: Oni, Joshua , Westbroek, Philippe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289692 , vital:56663 , xlink:href="https://doi.org/10.1002/1521-4109(200209)14"
- Description: The voltammetric behavior of vitamin B1 in alkaline medium at carbon paste electrode (CPE) is discussed. A method based on cyclic voltammetry for the determination of vitamin B1 at carbon paste electrode modified with manganese phthalocyanine (MnPc-CPE) is presented. In pH 10 buffer, the modified electrode showed catalytic activity towards the oxidation of vitamin B1 by considerably increasing the oxidation current of one of the observed waves compared to the oxidation current obtained at an unmodified electrode. The modified electrode was stable towards the determination of vitamin B1 compared to the unmodified electrode that is completely poisoned after a few scans. A linear relationship between the oxidation current and the concentration of vitamin B1 in solution was observed. The detection limit for vitamin B1 at the modified electrode was of the order of 10−5 mol dm−3. Commercial vitamin B1 tablets were analyzed using the modified electrodes.
- Full Text:
- Date Issued: 2002
Language as a ‘resource’ in South Africa: the economic life of language in a globalising society
- Authors: Wright, Laurence
- Date: 2002
- Language: English
- Type: text , article
- Identifier: vital:7035 , http://hdl.handle.net/10962/d1007370 , https://doi.org/10.1080/10131750285310031
- Description: preprint , We need to develop a much more refined and specific understanding of what is meant when people refer to language is a ‘resource’. If something can accurately be described as a resource, then by its very nature it carries with it or attracts, at least in potential, the social motivation associated with the utilization, development or exploitation of that resource. This is strikingly true where language is the resource in question, because language is so intimately bound up with human activity. Where it exists, such social motivation can be augmented and supported so as to realize the ends of language policy. Contrastingly, where it is seen that social motivation informing a particular language situation is at odds with the intent of language policy, then either implementation must retreat and move to other arenas, other points of influence, where intervention can be more effective, or those charged with implementation must resign themselves to costly and messy efforts to force unwanted change through legal authority.
- Full Text:
- Date Issued: 2002
- Authors: Wright, Laurence
- Date: 2002
- Language: English
- Type: text , article
- Identifier: vital:7035 , http://hdl.handle.net/10962/d1007370 , https://doi.org/10.1080/10131750285310031
- Description: preprint , We need to develop a much more refined and specific understanding of what is meant when people refer to language is a ‘resource’. If something can accurately be described as a resource, then by its very nature it carries with it or attracts, at least in potential, the social motivation associated with the utilization, development or exploitation of that resource. This is strikingly true where language is the resource in question, because language is so intimately bound up with human activity. Where it exists, such social motivation can be augmented and supported so as to realize the ends of language policy. Contrastingly, where it is seen that social motivation informing a particular language situation is at odds with the intent of language policy, then either implementation must retreat and move to other arenas, other points of influence, where intervention can be more effective, or those charged with implementation must resign themselves to costly and messy efforts to force unwanted change through legal authority.
- Full Text:
- Date Issued: 2002
Voltammetric detection of vitamin B1 at carbon paste electrodes and its determination in tablets
- Oni, Joshua, Westbroek, Philippe, Nyokong, Tebello
- Authors: Oni, Joshua , Westbroek, Philippe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289678 , vital:56662 , xlink:href="https://doi.org/10.1002/1521-4109(200209)14"
- Description: The voltammetric behavior of vitamin B1 in alkaline medium at carbon paste electrode (CPE) is discussed. A method based on cyclic voltammetry for the determination of vitamin B1 at carbon paste electrode modified with manganese phthalocyanine (MnPc-CPE) is presented. In pH 10 buffer, the modified electrode showed catalytic activity towards the oxidation of vitamin B1 by considerably increasing the oxidation current of one of the observed waves compared to the oxidation current obtained at an unmodified electrode. The modified electrode was stable towards the determination of vitamin B1 compared to the unmodified electrode that is completely poisoned after a few scans. A linear relationship between the oxidation current and the concentration of vitamin B1 in solution was observed. The detection limit for vitamin B1 at the modified electrode was of the order of 10−5 mol dm−3. Commercial vitamin B1 tablets were analyzed using the modified electrodes.
- Full Text:
- Date Issued: 2002
- Authors: Oni, Joshua , Westbroek, Philippe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289678 , vital:56662 , xlink:href="https://doi.org/10.1002/1521-4109(200209)14"
- Description: The voltammetric behavior of vitamin B1 in alkaline medium at carbon paste electrode (CPE) is discussed. A method based on cyclic voltammetry for the determination of vitamin B1 at carbon paste electrode modified with manganese phthalocyanine (MnPc-CPE) is presented. In pH 10 buffer, the modified electrode showed catalytic activity towards the oxidation of vitamin B1 by considerably increasing the oxidation current of one of the observed waves compared to the oxidation current obtained at an unmodified electrode. The modified electrode was stable towards the determination of vitamin B1 compared to the unmodified electrode that is completely poisoned after a few scans. A linear relationship between the oxidation current and the concentration of vitamin B1 in solution was observed. The detection limit for vitamin B1 at the modified electrode was of the order of 10−5 mol dm−3. Commercial vitamin B1 tablets were analyzed using the modified electrodes.
- Full Text:
- Date Issued: 2002
Synthesis, electrochemical and photochemical properties of unsymmetrically substituted zinc phthalocyanine complexes
- Matlaba, Pulane M, Nyokong, Tebello
- Authors: Matlaba, Pulane M , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289650 , vital:56658 , xlink:href="https://doi.org/10.1016/S0277-5387(02)01226-3"
- Description: The synthesis of symmetrically and unsymmetrically substituted zinc phthalocyanine (ZnPc) derivatives are reported. The ZnPc derivatives are synthesized by ring expansion of subphthalocyanine complexes. Ring substitution is effected with tert-butyl phenol, naphthol and hydroxybenzoic acid. Comparison of the redox potentials for complexes substituted with varying numbers of tert-butyl phenol: 1 (complex 5), 2 (complex 6), 3 (complex 7), 6 (complex 8) and 8 (complex 9) shows that the complexes with the highest number of substituents are more difficult to oxidize and easier to reduce. All the reported complexes are relatively photostable, with photobleaching quantum yields of the order of 10−5. Singlet oxygen quantum yields for the complexes ranged from 0.22 to 0.68.
- Full Text:
- Date Issued: 2002
- Authors: Matlaba, Pulane M , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289650 , vital:56658 , xlink:href="https://doi.org/10.1016/S0277-5387(02)01226-3"
- Description: The synthesis of symmetrically and unsymmetrically substituted zinc phthalocyanine (ZnPc) derivatives are reported. The ZnPc derivatives are synthesized by ring expansion of subphthalocyanine complexes. Ring substitution is effected with tert-butyl phenol, naphthol and hydroxybenzoic acid. Comparison of the redox potentials for complexes substituted with varying numbers of tert-butyl phenol: 1 (complex 5), 2 (complex 6), 3 (complex 7), 6 (complex 8) and 8 (complex 9) shows that the complexes with the highest number of substituents are more difficult to oxidize and easier to reduce. All the reported complexes are relatively photostable, with photobleaching quantum yields of the order of 10−5. Singlet oxygen quantum yields for the complexes ranged from 0.22 to 0.68.
- Full Text:
- Date Issued: 2002
Bodies in agitation: Wilma Cruise's recent works
- Authors: Schmahmann, Brenda
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147770 , vital:38670 , https://doi.org/10.1080/00043389.2002.11876996
- Description: Wilma Cruise is probably best known for Strike the Woman Strike the Rock (2000), a public work produced collaboratively with Marcus Holmes which commemorates the march of women on the Union Buildings on 9 August 1956 to protest against the pass laws. This government commission tallies with Cruise's longstanding interest in feminism. Also, through its incorpora tion of sound, the written word and projections of imagery, Strike the Woman Strike the Rock coheres with an interest in combining a diversity of media and art forms that has been evident in her work during the last few years.
- Full Text:
- Date Issued: 2017
- Authors: Schmahmann, Brenda
- Date: 2017
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/147770 , vital:38670 , https://doi.org/10.1080/00043389.2002.11876996
- Description: Wilma Cruise is probably best known for Strike the Woman Strike the Rock (2000), a public work produced collaboratively with Marcus Holmes which commemorates the march of women on the Union Buildings on 9 August 1956 to protest against the pass laws. This government commission tallies with Cruise's longstanding interest in feminism. Also, through its incorpora tion of sound, the written word and projections of imagery, Strike the Woman Strike the Rock coheres with an interest in combining a diversity of media and art forms that has been evident in her work during the last few years.
- Full Text:
- Date Issued: 2017
The distribution of platinum group elements in the Insizwa lobe, Mount Ayliff Complex, South Africa: implications for Ni-Cu-PGE sulfide exploration in the Karoo igneous province
- Maier, W D, Marsh, Julian S, Barnes, Sarah-Jane, Dodd, D C
- Authors: Maier, W D , Marsh, Julian S , Barnes, Sarah-Jane , Dodd, D C
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150353 , vital:38969 , https://0-doi.org.wam.seals.ac.za/10.2113/gsecongeo.97.6.1293
- Description: The Mount Ayliff Complex of the Eastern Cape province of South Africa is a layered intrusion of some 800 km2 surface area and up to 1,200 m thickness. On the basis of compositional similarities and spatial association, it is generally interpreted to form part of the Karoo igneous province. Similarities between the Mount Ayliff Complex and the staging chambers and feeder conduits to flood basalts that host magmatic sulfide ores elsewhere in the world suggest that the Mount Ayliff Complex may have an enhanced potential for Noril’sk-Talnakh–type massive Ni-Cu sulfide ores, an idea that is supported by the well-known sulfide occurrence at Waterfall Gorge.
- Full Text: false
- Date Issued: 2002
- Authors: Maier, W D , Marsh, Julian S , Barnes, Sarah-Jane , Dodd, D C
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/150353 , vital:38969 , https://0-doi.org.wam.seals.ac.za/10.2113/gsecongeo.97.6.1293
- Description: The Mount Ayliff Complex of the Eastern Cape province of South Africa is a layered intrusion of some 800 km2 surface area and up to 1,200 m thickness. On the basis of compositional similarities and spatial association, it is generally interpreted to form part of the Karoo igneous province. Similarities between the Mount Ayliff Complex and the staging chambers and feeder conduits to flood basalts that host magmatic sulfide ores elsewhere in the world suggest that the Mount Ayliff Complex may have an enhanced potential for Noril’sk-Talnakh–type massive Ni-Cu sulfide ores, an idea that is supported by the well-known sulfide occurrence at Waterfall Gorge.
- Full Text: false
- Date Issued: 2002
Interaction of sulfur dioxide and cyanide with cobalt (II) tetrasulfophthalocyanine in aqueous media
- Thamae, Mamothibe, Nyokong, Tebello
- Authors: Thamae, Mamothibe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289595 , vital:56652 , xlink:href="https://doi.org/10.1016/S0277-5387(01)00968-8"
- Description: Kinetic and equilibrium studies for the coordination of cyanide or sulfur dioxide to the cobalt(II) tetrasulfophthalocyanine ([CoTSPc]4−) complex are reported. The equilibrium constant for the coordination of the cyanide under pH 11 conditions and an oxygen atmosphere, and the formation of [(CN−)2Co(III)TSPc]5− species, was found to be 2.1×101 dm3 mol−1 and the rate constant, kf was found to be 7.4 dm3 mol−1 s−1. Similarly, the coordination of SO2 to [CoTSPc]4− occurred with an equilibrium constant of 8.7×101 dm3 mol−1 and a rate constant of 2.1×102 dm3 mol−1 s−1, at pH 11. These rate and equilibrium constants represent the coordination of the second cyanide or sulfur dioxide ligands to the [CoTSPc]4− species. Coordination of the first ligand occurred faster than that of the second ligand in both cases. The coordination is accompanied by the oxidation of the central Co(II) metal with the formation of a Co(III) tetrasulfophthalocyanine species.
- Full Text:
- Date Issued: 2002
Interaction of sulfur dioxide and cyanide with cobalt (II) tetrasulfophthalocyanine in aqueous media
- Authors: Thamae, Mamothibe , Nyokong, Tebello
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/289595 , vital:56652 , xlink:href="https://doi.org/10.1016/S0277-5387(01)00968-8"
- Description: Kinetic and equilibrium studies for the coordination of cyanide or sulfur dioxide to the cobalt(II) tetrasulfophthalocyanine ([CoTSPc]4−) complex are reported. The equilibrium constant for the coordination of the cyanide under pH 11 conditions and an oxygen atmosphere, and the formation of [(CN−)2Co(III)TSPc]5− species, was found to be 2.1×101 dm3 mol−1 and the rate constant, kf was found to be 7.4 dm3 mol−1 s−1. Similarly, the coordination of SO2 to [CoTSPc]4− occurred with an equilibrium constant of 8.7×101 dm3 mol−1 and a rate constant of 2.1×102 dm3 mol−1 s−1, at pH 11. These rate and equilibrium constants represent the coordination of the second cyanide or sulfur dioxide ligands to the [CoTSPc]4− species. Coordination of the first ligand occurred faster than that of the second ligand in both cases. The coordination is accompanied by the oxidation of the central Co(II) metal with the formation of a Co(III) tetrasulfophthalocyanine species.
- Full Text:
- Date Issued: 2002
The influence of education on the interpretation of pharmaceutical pictograms for communicating medicine instructions:
- Dowse, Roslind, Ehlers, Martina S
- Authors: Dowse, Roslind , Ehlers, Martina S
- Date: 2003
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/157014 , vital:40079 , DOI 10.1211/002235702810
- Description: To assess the influence of formal education on the interpretation of pharmaceutical pictograms.
- Full Text:
- Date Issued: 2003
- Authors: Dowse, Roslind , Ehlers, Martina S
- Date: 2003
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/157014 , vital:40079 , DOI 10.1211/002235702810
- Description: To assess the influence of formal education on the interpretation of pharmaceutical pictograms.
- Full Text:
- Date Issued: 2003
Maybe the courts are not such a Bleak House after all - or please sir, I want some more copyright
- Authors: Glover, Graham B
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70841 , vital:29749 , https://heinonline.org/HOL/P?h=hein.journals/soaf119&i=101
- Description: In our advanced technological age the law of copyright faces tremendous challenges. In particular, the Internet has created serious problems for those who wish to enforce their proprietary rights, and to protect their textual (and other) creations from unregulated and uninhibited reproduction.
- Full Text: false
- Date Issued: 2002
- Authors: Glover, Graham B
- Date: 2002
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/70841 , vital:29749 , https://heinonline.org/HOL/P?h=hein.journals/soaf119&i=101
- Description: In our advanced technological age the law of copyright faces tremendous challenges. In particular, the Internet has created serious problems for those who wish to enforce their proprietary rights, and to protect their textual (and other) creations from unregulated and uninhibited reproduction.
- Full Text: false
- Date Issued: 2002
The role and value of savanna non-timber forest products to rural households in the Kat River Valley, South Africa
- Shackleton, Charlie M, Shackleton, Sheona E, Ntshudu, M, Ntzebeza, J
- Authors: Shackleton, Charlie M , Shackleton, Sheona E , Ntshudu, M , Ntzebeza, J
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182820 , vital:43882 , xlink:href="https://www.cabdirect.org/cabdirect/abstract/20023145773"
- Description: The majority of South Africans reside in rural areas characterized by limited infrastructure and employment opportunities. Many, therefore, make extensive use of non-timber-forest products (NTFPs) as part of their daily livelihoods. However, until recently, there were relatively few quantitative studies on resources used, amounts and frequencies. This is especially so for the savanna biome in South Africa, even though it is the largest biome. This paper presents data from a quantitative study of resource use and value in three villages situated in the savannas of the poorest province of South Africa. The results demonstrated widespread use of a wide variety of NTFPs. There were no households that did not make use of at least one NTFP from the surrounding woodlands. The five contributing most to the total gross value per household were fuelwood, wild herbs, wild fruits, bushmeat and honey beer. The mean gross annual direct-use value at the three villages ranged from US$211 to US$324 per household, averaged across user and non-user households. The direct-use value to user households was approximately double this. The net value differed between specific NTFPs because of differential labour input. The net value represented between 39 and 86% of the gross value, with a mean of 63%. However, the use of opportunity costs of labour in such areas requires examination.
- Full Text:
- Date Issued: 2002
- Authors: Shackleton, Charlie M , Shackleton, Sheona E , Ntshudu, M , Ntzebeza, J
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182820 , vital:43882 , xlink:href="https://www.cabdirect.org/cabdirect/abstract/20023145773"
- Description: The majority of South Africans reside in rural areas characterized by limited infrastructure and employment opportunities. Many, therefore, make extensive use of non-timber-forest products (NTFPs) as part of their daily livelihoods. However, until recently, there were relatively few quantitative studies on resources used, amounts and frequencies. This is especially so for the savanna biome in South Africa, even though it is the largest biome. This paper presents data from a quantitative study of resource use and value in three villages situated in the savannas of the poorest province of South Africa. The results demonstrated widespread use of a wide variety of NTFPs. There were no households that did not make use of at least one NTFP from the surrounding woodlands. The five contributing most to the total gross value per household were fuelwood, wild herbs, wild fruits, bushmeat and honey beer. The mean gross annual direct-use value at the three villages ranged from US$211 to US$324 per household, averaged across user and non-user households. The direct-use value to user households was approximately double this. The net value differed between specific NTFPs because of differential labour input. The net value represented between 39 and 86% of the gross value, with a mean of 63%. However, the use of opportunity costs of labour in such areas requires examination.
- Full Text:
- Date Issued: 2002
Growth and fruit production of Sclerocarya birrea in the South African lowveld
- Authors: Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181618 , vital:43752 , xlink:href="https://doi.org/10.1023/A:1020579213024"
- Description: Sclerocarya birrea (A.Rich.) Hochst. subsp. caffra (Sond.) Kokwaro. is a common species throughout the semiarid, deciduous savannas of much of sub-Saharan Africa. It is a favoured species and is frequently maintained in homestead plots and arable fields in an agroforestry situation. Although the abundance and popularity of this species has led to several initiatives to commercialise a number of marula products, the sustainability of the resource base with respect to fruit production has not been considered. This paper reports on a field experiment that monitored growth rates and fruit production of a sample of adult trees from several wild populations. Mean fruit production was 36.8 kg per tree in the first year, and negligible in the second. This was considerably less than previous estimates, which were based largely on small samples or anecdotal reports. The maximum recorded yield was 416.6 kg per tree. Fruit production was positively related to the size of the tree. Growth rates of adult trees were slow. There was a strong positive relationship between mean annual diameter increment and stem diameter. The slow growth rates and low fruit yields indicate that more attention is required regarding the sustainability of there source and its ability to provide sufficient fruit for the growing subsistence and commercial demand at both local and national scales.
- Full Text:
- Date Issued: 2002
- Authors: Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181618 , vital:43752 , xlink:href="https://doi.org/10.1023/A:1020579213024"
- Description: Sclerocarya birrea (A.Rich.) Hochst. subsp. caffra (Sond.) Kokwaro. is a common species throughout the semiarid, deciduous savannas of much of sub-Saharan Africa. It is a favoured species and is frequently maintained in homestead plots and arable fields in an agroforestry situation. Although the abundance and popularity of this species has led to several initiatives to commercialise a number of marula products, the sustainability of the resource base with respect to fruit production has not been considered. This paper reports on a field experiment that monitored growth rates and fruit production of a sample of adult trees from several wild populations. Mean fruit production was 36.8 kg per tree in the first year, and negligible in the second. This was considerably less than previous estimates, which were based largely on small samples or anecdotal reports. The maximum recorded yield was 416.6 kg per tree. Fruit production was positively related to the size of the tree. Growth rates of adult trees were slow. There was a strong positive relationship between mean annual diameter increment and stem diameter. The slow growth rates and low fruit yields indicate that more attention is required regarding the sustainability of there source and its ability to provide sufficient fruit for the growing subsistence and commercial demand at both local and national scales.
- Full Text:
- Date Issued: 2002
Growth patterns of Pterocarpus angolensis in savannas of the South African lowveld
- Authors: Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182373 , vital:43824 , xlink:href="https://doi.org/10.1016/S0378-1127(01)00676-4"
- Description: Pterocarpus angolensis D.C. is one of the most valuable indigenous timber species on the African continent south of the equator. Because of its high value, it is actively sought after in a number of countries, and wild populations are diminishing. However, attempts at artificial germination and growth trials have yielded poor results, thus, emphasis needs to be placed on sustainable management of existing populations. Success of in situ management will be enhanced if based on reliable data and knowledge regarding the growth patterns of this species within specific localities and countries. Such comprehensive data are lacking for several countries, including South Africa. This paper presents empirical data on a number of studies investigating the growth patterns of P. angolensis in the central lowveld savannas of South Africa, including phenology, annual diameter increment, size class structure, size of reproductive maturity, and morphometric relationships. The size class profile indicated that there was adequate recruitment of P. angolensis, but with constricted through growth from the suffrutex stage to the sapling stage. A small proportion of individuals attained reproductive maturity at 8 cm diameter, but most were bigger. All stems were reproductively mature by 26 cm diameter. This is below the minimum size for harvesting which is dictated by the need for a well developed heartwood. Annual growth was strongly related to stem size and rainfall during the growing season. Basal area increment of small stems was approximately four times greater than mature stems, and declined with increasing stem size. Over the 6-year-period and across all stem sizes, mean diameter increment was 4.5 mm per year. This rate is towards the lower end of the range of reported growth rates from other countries, and poses particular challenges for the sustainable management of this species in South African savannas.
- Full Text:
- Date Issued: 2002
- Authors: Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/182373 , vital:43824 , xlink:href="https://doi.org/10.1016/S0378-1127(01)00676-4"
- Description: Pterocarpus angolensis D.C. is one of the most valuable indigenous timber species on the African continent south of the equator. Because of its high value, it is actively sought after in a number of countries, and wild populations are diminishing. However, attempts at artificial germination and growth trials have yielded poor results, thus, emphasis needs to be placed on sustainable management of existing populations. Success of in situ management will be enhanced if based on reliable data and knowledge regarding the growth patterns of this species within specific localities and countries. Such comprehensive data are lacking for several countries, including South Africa. This paper presents empirical data on a number of studies investigating the growth patterns of P. angolensis in the central lowveld savannas of South Africa, including phenology, annual diameter increment, size class structure, size of reproductive maturity, and morphometric relationships. The size class profile indicated that there was adequate recruitment of P. angolensis, but with constricted through growth from the suffrutex stage to the sapling stage. A small proportion of individuals attained reproductive maturity at 8 cm diameter, but most were bigger. All stems were reproductively mature by 26 cm diameter. This is below the minimum size for harvesting which is dictated by the need for a well developed heartwood. Annual growth was strongly related to stem size and rainfall during the growing season. Basal area increment of small stems was approximately four times greater than mature stems, and declined with increasing stem size. Over the 6-year-period and across all stem sizes, mean diameter increment was 4.5 mm per year. This rate is towards the lower end of the range of reported growth rates from other countries, and poses particular challenges for the sustainable management of this species in South African savannas.
- Full Text:
- Date Issued: 2002
A comparison of anthropogenic and elephant disturbance on Acacia xanthophloea (fever tree) populations in the Lowveld, South Africa
- Botha, Jenny, Witkowski, Ed T F, Shackleton, Charlie M
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181629 , vital:43753 , xlink:href="https://doi.org/10.4102/koedoe.v45i1.10"
- Description: Acacia xanthophloea (the ‘fever tree’) is a popular medicinal species that is traded widely in South Africa. Although it occurs throughout southern Africa, there is increasing pressure on its riverine and marshy habitats. This study compares the impact of harvesting on an A. xanthophloea population located on private land near Komatipoort, Mpumalanga, with two protected populations situated within the Kruger National Park. The densities of the harvested and protected populations were similar (84±8 trees/ha and 85±20 trees/ha, respectively). There were fluctuations in the quotients between frequencies of trees in successive diameter classes, which is common in savanna where high levels of fire, mega-herbivore and anthropogenic disturbance are experienced. The extent of stem damage (stripping of bark and breakage) by elephants in the protected area was significantly higher than the extent of harvesting on private land, although the degree of damage was relatively low, with only 7 % of the populations having been damaged at rates >26 %. The degree of harvesting on private land was relatively low, with the majority of trees having been harvested at rates of less than 10 % of the stem below 2 m. Despite this, ringbarking had occurred (4 %). The basal diameters and heights were significantly lower in the protected population than in the harvested one, suggesting that over time elephant impact was the more severe disturbance. Acacia xanthophloea exhibited high resilience to disturbance, with all the elephant damaged trees and harvested individuals surviving. However, the mean bark thickness measured in local markets (6.3±1.4 mm) was significantly lower than that measured in either the harvested (12.4±1.0 mm) or the KNP (10.3±0.8 mm) populations. As harvesters tend to select the largest individuals in a population to maximise their financial returns, this could mean that smaller individuals are being harvested, and/or bark is not being given sufficient time to grow back after harvesting. Acacia xanthophloea outside protected areas thus need to be monitored and the management improved, preferably in conjunction with the resource users. In addition, traditional healers, those selling medicinal plants and other members of the community need to continue to be encouraged to cultivate this fast growing species.
- Full Text:
- Date Issued: 2002
- Authors: Botha, Jenny , Witkowski, Ed T F , Shackleton, Charlie M
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/181629 , vital:43753 , xlink:href="https://doi.org/10.4102/koedoe.v45i1.10"
- Description: Acacia xanthophloea (the ‘fever tree’) is a popular medicinal species that is traded widely in South Africa. Although it occurs throughout southern Africa, there is increasing pressure on its riverine and marshy habitats. This study compares the impact of harvesting on an A. xanthophloea population located on private land near Komatipoort, Mpumalanga, with two protected populations situated within the Kruger National Park. The densities of the harvested and protected populations were similar (84±8 trees/ha and 85±20 trees/ha, respectively). There were fluctuations in the quotients between frequencies of trees in successive diameter classes, which is common in savanna where high levels of fire, mega-herbivore and anthropogenic disturbance are experienced. The extent of stem damage (stripping of bark and breakage) by elephants in the protected area was significantly higher than the extent of harvesting on private land, although the degree of damage was relatively low, with only 7 % of the populations having been damaged at rates >26 %. The degree of harvesting on private land was relatively low, with the majority of trees having been harvested at rates of less than 10 % of the stem below 2 m. Despite this, ringbarking had occurred (4 %). The basal diameters and heights were significantly lower in the protected population than in the harvested one, suggesting that over time elephant impact was the more severe disturbance. Acacia xanthophloea exhibited high resilience to disturbance, with all the elephant damaged trees and harvested individuals surviving. However, the mean bark thickness measured in local markets (6.3±1.4 mm) was significantly lower than that measured in either the harvested (12.4±1.0 mm) or the KNP (10.3±0.8 mm) populations. As harvesters tend to select the largest individuals in a population to maximise their financial returns, this could mean that smaller individuals are being harvested, and/or bark is not being given sufficient time to grow back after harvesting. Acacia xanthophloea outside protected areas thus need to be monitored and the management improved, preferably in conjunction with the resource users. In addition, traditional healers, those selling medicinal plants and other members of the community need to continue to be encouraged to cultivate this fast growing species.
- Full Text:
- Date Issued: 2002
The identification of the UV degradants of melatonin and their ability to scavenge free radicals
- Maharaj, Deepa S, Anoopkumar-Dukie, Shailendra, Glass, Beverley D, Antunes, Edith M, Lack, Barbara A, Walker, Roderick B, Daya, Santylal
- Authors: Maharaj, Deepa S , Anoopkumar-Dukie, Shailendra , Glass, Beverley D , Antunes, Edith M , Lack, Barbara A , Walker, Roderick B , Daya, Santylal
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184303 , vital:44198 , xlink:href="https://doi.org/10.1034/j.1600-079X.2002.01866.x"
- Description: Ultraviolet (UV) light is known to induce the generation of free radicals in biological tissues such as skin. Of these free radicals, the O2–· and particularly the ·OH radical can induce cellular damage including lipid peroxidation. Thus, the use of antioxidants to prevent such damage induced by UV irradiation has received much attention recently. One such antioxidant, which has the potential to be incorporated into sunscreens, is the pineal secretory product melatonin. One of the concerns of using melatonin in sunscreens is its photostability. In the present study, we investigated the photostability of melatonin subjected to UV irradiation. In addition, we used liquid chromatography mass spectrometry (LC-MS) to identify the degradants and we also assessed the ability of the degradants to inhibit O2–· generation as well as lipid peroxidation in rat brain homogenate. The results show that UV irradiation of melatonin (0.1 mg/mL) using a 400-W lamp for 2 hr caused a significant decline of melatonin to 18% of its original concentration after 20 min, with the decline continuing until the melatonin concentration reaches zero at 120 min. The LC-MS results show that the degradants of melatonin are 6-hydroxymelatonin and N1-acetyl-N2-formyl-5-methoxykynurenamine (AFMK). These degradants were able to provide equipotent activity against potassium cyanide (KCN)-induced superoxide generation compared to non-irradiated melatonin. Thus, the study shows that although melatonin is rapidly degraded by UV irradiation, the degradants retain antioxidant activity, making melatonin a likely candidate for inclusion in sunscreens.
- Full Text:
- Date Issued: 2002
- Authors: Maharaj, Deepa S , Anoopkumar-Dukie, Shailendra , Glass, Beverley D , Antunes, Edith M , Lack, Barbara A , Walker, Roderick B , Daya, Santylal
- Date: 2002
- Subjects: To be catalogued
- Language: English
- Type: text , article
- Identifier: http://hdl.handle.net/10962/184303 , vital:44198 , xlink:href="https://doi.org/10.1034/j.1600-079X.2002.01866.x"
- Description: Ultraviolet (UV) light is known to induce the generation of free radicals in biological tissues such as skin. Of these free radicals, the O2–· and particularly the ·OH radical can induce cellular damage including lipid peroxidation. Thus, the use of antioxidants to prevent such damage induced by UV irradiation has received much attention recently. One such antioxidant, which has the potential to be incorporated into sunscreens, is the pineal secretory product melatonin. One of the concerns of using melatonin in sunscreens is its photostability. In the present study, we investigated the photostability of melatonin subjected to UV irradiation. In addition, we used liquid chromatography mass spectrometry (LC-MS) to identify the degradants and we also assessed the ability of the degradants to inhibit O2–· generation as well as lipid peroxidation in rat brain homogenate. The results show that UV irradiation of melatonin (0.1 mg/mL) using a 400-W lamp for 2 hr caused a significant decline of melatonin to 18% of its original concentration after 20 min, with the decline continuing until the melatonin concentration reaches zero at 120 min. The LC-MS results show that the degradants of melatonin are 6-hydroxymelatonin and N1-acetyl-N2-formyl-5-methoxykynurenamine (AFMK). These degradants were able to provide equipotent activity against potassium cyanide (KCN)-induced superoxide generation compared to non-irradiated melatonin. Thus, the study shows that although melatonin is rapidly degraded by UV irradiation, the degradants retain antioxidant activity, making melatonin a likely candidate for inclusion in sunscreens.
- Full Text:
- Date Issued: 2002